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1.3.99.25: carvone reductase

This is an abbreviated version!
For detailed information about carvone reductase, go to the full flat file.

Reaction

(+)-dihydrocarvone
+
acceptor
=
(-)-Carvone
 +
reduced acceptor

ECTree

     1 Oxidoreductases
         1.3 Acting on the CH-CH group of donors
             1.3.99 With unknown physiological acceptors
                1.3.99.25 carvone reductase

Substrates Products

Substrates Products on EC 1.3.99.25 - carvone reductase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(4R)-carvone + reduced acceptor
?
show the reaction diagram
-
transient accumulation of (1R,4R)-dihydrocarvone is observed. Upon longer incubation, this compound is converted mainly into (1R,2R,4R)-dihydrocarveol and traces of (1R,2S,4R)-neo-dihydrocarveol
-
-
?
(4S)-carvone + reduced acceptor
(1R,4S)-iso-dihydrocarvone + acceptor
show the reaction diagram
-
under aerobic conditions, only traces of (iso-)dihydrocarvone accumulate. Under anaerobic conditions much larger quantities of these compounds accumulate. The enzyme requires an unknown cofactor, which is different from NAD+, NADP+ or a flavin
-
-
?
additional information
?
-