1.3.98.7: [mycofactocin precursor peptide]-tyrosine decarboxylase
This is an abbreviated version!
For detailed information about [mycofactocin precursor peptide]-tyrosine decarboxylase, go to the full flat file.
Reaction
Synonyms
mftC, MtfC, mycofactocin maturase, Rv0693
ECTree
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Substrates Products
Substrates Products on EC 1.3.98.7 - [mycofactocin precursor peptide]-tyrosine decarboxylase
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REACTION DIAGRAM
C-terminal [mycofactocin precursor peptide MftA]-glycyl-L-valyl-L-tyrosine + S-adenosyl-L-methionine
C-terminal [mycofactocin precursor peptide MftA]-glycyl-L-valyl-4-[2-aminoethenyl]phenol + CO2 + 5'-deoxyadenosine + L-methionine
C-terminal [mycofactocin precursor peptide]-glycyl-L-valyl-L-tyrosine + S-adenosyl-L-methionine
C-terminal [mycofactocin precursor peptide]-glycyl-L-valyl-4-[2-aminoethenyl]phenol + CO2 + 5'-deoxyadenosine + L-methionine
C-terminal [mycofactocin precursor peptide MftA]-glycyl-L-valyl-L-tyrosine + S-adenosyl-L-methionine
C-terminal [mycofactocin precursor peptide MftA]-glycyl-L-valyl-4-[2-aminoethenyl]phenol + CO2 + 5'-deoxyadenosine + L-methionine
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C-terminal [mycofactocin precursor peptide MftA]-glycyl-L-valyl-L-tyrosine + S-adenosyl-L-methionine
C-terminal [mycofactocin precursor peptide MftA]-glycyl-L-valyl-4-[2-aminoethenyl]phenol + CO2 + 5'-deoxyadenosine + L-methionine
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?
C-terminal [mycofactocin precursor peptide]-glycyl-L-valyl-4-[2-aminoethenyl]phenol + CO2 + 5'-deoxyadenosine + L-methionine
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?
C-terminal [mycofactocin precursor peptide]-glycyl-L-valyl-L-tyrosine + S-adenosyl-L-methionine
C-terminal [mycofactocin precursor peptide]-glycyl-L-valyl-4-[2-aminoethenyl]phenol + CO2 + 5'-deoxyadenosine + L-methionine
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enzyme additionally catalyzes SAM-dependent C-C bond formation between the Cbeta of the penultimate valine and the Calpha of the former tyrosine, forming a 3-amino-5-[(4-hydroxyphenyl) methyl]-4,4-dimethyl-2-pyrrolidinone moiety, i.e. MftA*, reaction of EC 4.1.99.26
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additional information
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enzyme additionally catalyzes SAM-dependent C-C bond formation between the Cbeta of the penultimate valine and the Calpha of the former tyrosine, forming a 3-amino-5-[(4-hydroxyphenyl) methyl]-4,4-dimethyl-2-pyrrolidinone moiety, i.e. MftA*, reaction of EC 4.1.99.26
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