1.3.1.82: (-)-isopiperitenone reductase
This is an abbreviated version!
For detailed information about (-)-isopiperitenone reductase, go to the full flat file.
Word Map on EC 1.3.1.82
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1.3.1.82
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reductases
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monoterpene
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mentha
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ketoreduction
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pinpointing
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alkenes
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menthone
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peppermint
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ketoreductases
- 1.3.1.82
- reductases
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monoterpene
- mentha
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ketoreduction
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pinpointing
- alkenes
- menthone
- peppermint
- ketoreductases
Reaction
Synonyms
IPR, isopiperitenone reductase, More, NADPH-dependent isopiperitenone reductase
ECTree
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Substrates Products
Substrates Products on EC 1.3.1.82 - (-)-isopiperitenone reductase
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REACTION DIAGRAM
(2S,5R)-5-methyl-2-(propan-2-yl)cyclohexan-1-one + NADP+
(2S,5R)-5-methyl-2-(propan-2-yl)cyclohexan-1-ol + (1S,2R,5R)-5-methyl-2-(propan-2-yl)cyclohexan-1-ol + NADPH + H+
reaction of enzyme mutant E238Y, not of the wild-type enzyme
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2,6,6-trimethyl-4-oxocyclohex-2-ene-1-carbaldehyde + NADP+
2,2,6-trimethyl-4-oxocyclohexane-1-carbaldehyde + NADPH + H+
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3,5,5-trimethyl-4-(propan-2-yl)cyclohex-2-en-1-one + NADP+
3,3,5-trimethyl-4-(propan-2-yl)cyclohexan-1-one + NADPH + H+
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3,5,5-trimethylcyclohex-2-en-1-one + NADP+
3,3,5-trimethylcyclohexan-1-one + NADPH + H+
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3,5-dimethylcyclohex-2-en-1-one + NADP+
3,5-dimethylcyclohexan-1-one + NADPH + H+
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3-methyl-6-(prop-1-en-2-yl)cyclohex-2-en-1-one + NADP+
5-methyl-2-(prop-1-en-2-yl)cyclohexan-1-one + NADPH + H+
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3-methyl-6-(propan-2-yl)cyclohex-2-en-1-one + NADP+
5-methyl-2-(propan-2-yl)cyclohexan-1-one + NADPH + H+
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(-)-isopiperitenone + NADPH + H+
(+)-cis-isopulegone + NADP+
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the soluble NADPH-dependent, endocyclic double-bond reductase reduces (-)-isopiperitenone to (+)-cis-isopulegone, pathways of monoterpene biosynthesis, overview
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(-)-isopiperitenone + NADPH + H+
(+)-cis-isopulegone + NADP+
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(-)-isopiperitenone + NADPH + H+
(+)-cis-isopulegone + NADP+
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pathways of monoterpene biosynthesis, overview
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(-)-isopiperitenone + NADPH + H+
(+)-cis-isopulegone + NADP+
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the soluble NADPH-dependent, endocyclic double-bond reductase reduces (-)-isopiperitenone to (+)-cis-isopulegone, pathways of monoterpene biosynthesis, overview
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(-)-isopiperitenone + NADPH + H+
(+)-cis-isopulegone + NADP+
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regiospecific and stereospecific reductase
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GC-MS analysis shows that pulegone and menthone with 87.92% of total compositions are the major compounds in Mentha pulegium at flowering stage
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additional information
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compound analysis by GS-MS. 3-methyl-6-(prop-1-en-2-yl)cyclohex-2-en-1-one is a poor substrate for enzyme mutant E238Y. Substrate specificity of wild-type and mutant enzymes and ligand binding structure analysis, overview
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