1.3.1.123: 8-oxogeranial reductase

This is an abbreviated version!
For detailed information about 8-oxogeranial reductase, go to the full flat file.

Reaction

Synonyms

AmISY, iridoid synthase, IS1, IS2, ISY, MOR, multisubstrate oxido-reductase

ECTree

     1 Oxidoreductases

         1.3 Acting on the CH-CH group of donors

             1.3.1 With NAD⁺ or NADP⁺ as acceptor

                1.3.1.123 8-oxogeranial reductase

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Results	in table
1	AA Sequence
3	Cloned(Commentary)
3	Cofactor
1	Crystallization (Commentary)
1	General Information
4	kcat/KM [mM/s]
6	KM Value [mM]
1	Localization
3	Natural Substrates/ Products (Substrates)
4	Organism
2	Protein Variants
3	Purification (Commentary)
1	Reaction
4	Reference
4	Source Tissue
4	Substrates and Products (Substrate)
3	Subunits
10	Synonyms
1	Systematic Name
6	Turnover Number [1/s]

Systematic Name

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Systematic Name on EC 1.3.1.123 - 8-oxogeranial reductase

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SYSTEMATIC NAME

IUBMB Comments

(R)-8-oxocitronellyl enol:NADP+ oxidoreductase

The enzyme, characterized from the plant Antirrhinum majus (snapdragon), is involved in biosynthesis of 7-epi-iridoids such as antirrhinoside. The enzyme catalyses the stereospecific reduction of 8-oxogeranial, forming an unstable product that in the absence of additional cylases undergoes spontaneous cyclization to (-)-cis,trans-nepetalactol. cf. EC 1.3.1.122, (S)-8-oxocitronellyl enol synthase.