1.3.1.123: 8-oxogeranial reductase
This is an abbreviated version!
For detailed information about 8-oxogeranial reductase, go to the full flat file.
Reaction
Synonyms
AmISY, iridoid synthase, IS1, IS2, ISY, MOR, multisubstrate oxido-reductase
ECTree
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Systematic Name
Systematic Name on EC 1.3.1.123 - 8-oxogeranial reductase
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(R)-8-oxocitronellyl enol:NADP+ oxidoreductase
The enzyme, characterized from the plant Antirrhinum majus (snapdragon), is involved in biosynthesis of 7-epi-iridoids such as antirrhinoside. The enzyme catalyses the stereospecific reduction of 8-oxogeranial, forming an unstable product that in the absence of additional cylases undergoes spontaneous cyclization to (-)-cis,trans-nepetalactol. cf. EC 1.3.1.122, (S)-8-oxocitronellyl enol synthase.