1.2.98.1: formaldehyde dismutase

This is an abbreviated version!
For detailed information about formaldehyde dismutase, go to the full flat file.

Word Map on EC 1.2.98.1

1.2.98.1

methanol

putida

dismutation

horse

nicotinoproteins

methylobacterium

formic

detoxifying

zinc-containing

synthesis

amycolatopsis

erythropolis

lyophilized

rhodococcus

one-half

benzaldehyde

methanolica

dehydrogenation

groesl

enzyme-bound

dissimilate

degradation

Reaction

2 formaldehyde +

Synonyms

aldehyde dismutase, cannizzanase, dismutase, formaldehyde, EC 1.2.99.4, FDM, Fdm1, Fdm2, Fdm3, N,N9-dimethyl-4-nitrosoaniline oxidoreductase

ECTree

1 Oxidoreductases

1.2 Acting on the aldehyde or oxo group of donors

1.2.98 With other, known, physiological acceptors

1.2.98.1 formaldehyde dismutase

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Results	in table
470	AA Sequence
4	Application
1	CAS Registry Number
7	Cloned(Commentary)
4	Cofactor
2	Crystallization (Commentary)
3	Expression
4	General Information
1	General Stability
14	Inhibitors
3	kcat/KM [mM/s]
2	Ki Value [mM]
11	KM Value [mM]
6	Metals/Ions
14	Molecular Weight [Da]
10	Natural Substrates/ Products (Substrates)
57	Organism
4	Pathway
4	pH Optimum
1	pH Range
1	pH Stability
1	pI Value
8	Purification (Commentary)
1	Reaction
6	Reaction Type
30	Reference
1	Source Tissue
5	Specific Activity [micromol/min/mg]
88	Substrates and Products (Substrate)
13	Subunits
15	Synonyms
1	Systematic Name
5	Temperature Optimum [°C]
5	Temperature Stability [°C]
6	Turnover Number [1/s]

Systematic Name

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Systematic Name on EC 1.2.98.1 - formaldehyde dismutase

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formaldehyde:formaldehyde oxidoreductase

The enzyme contains a tightly but noncovalently bound NADP(H) cofactor, as well as Zn2+ and Mg2+. Enzyme-bound NADPH formed by oxidation of formaldehyde to formate is oxidized back to NADP+ by reaction with a second formaldehyde, yielding methanol. The enzyme from the bacterium Mycobacterium sp. DSM 3803 also catalyses the reactions of EC 1.1.99.36, alcohol dehydrogenase (nicotinoprotein) and EC 1.1.99.37, methanol dehydrogenase (nicotinoprotein) [3]. Formaldehyde and acetaldehyde can act as donors; formaldehyde, acetaldehyde and propanal can act as acceptors [1,2].