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1.14.16.5: alkylglycerol monooxygenase

This is an abbreviated version!
For detailed information about alkylglycerol monooxygenase, go to the full flat file.

Word Map on EC 1.14.16.5

Reaction

1-O-alkyl-sn-glycerol
+
a 5,6,7,8-tetrahydropteridine
+
O2
=
1-O-(1-hydroxyalkyl)-sn-glycerol
+
a 4a-hydroxy-5,6,7,8-tetrahydropteridine

Synonyms

AGMO, alkylglycerol mono-oxygenase, alkylglycerol monooxygenase, EC 1.14.99.17, glyceryl ether hydroxylase, glyceryl ether monooxygenase, glyceryl ether oxidase, glyceryl ether oxygenase, glyceryl ether-cleaving enzyme, glyceryl etherase, glyceryl-ether cleaving enzyme, O-alkylglycerol monooxygenase, oxygenase, glyceryl ether mono-, PRUB680

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.16 With reduced pteridine as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.16.5 alkylglycerol monooxygenase

Substrates Products

Substrates Products on EC 1.14.16.5 - alkylglycerol monooxygenase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(2R)-3-hexadecyloxypropan-1,2-diol + 2-amino-5,6,7,8-tetrahydropteridin-4-one + O2
?
show the reaction diagram
-
-
-
-
?
(2R)-3-octadecyloxypropan-1,2-diol + 2-amino-5,6,7,8-tetrahydropteridin-4-one + O2
?
show the reaction diagram
-
-
-
-
?
(2RS,1'R)-[1-3H1]-hexadecyloxypropane-1,2-diol + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
only 6.5% release of the tritium after 20 min, reaction is stereospecific for the pro-HS hydrogen
-
-
?
(2RS,1'S)-[1-3H1]-hexadecyloxypropane-1,2-diol + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
release of 37% of the tritium after 20 min, reaction is stereospecific for the pro-HS hydrogen
-
-
?
(2S)-3-hexadecyloxypropan-1,2-diol + 2-amino-5,6,7,8-tetrahydropteridin-4-one + O2
?
show the reaction diagram
-
the oxygen transfer to 1'C of the aliphatic side-chain is highly stereospecific
-
-
?
(2S)-3-octadecyloxypropan-1,2-diol + 2-amino-5,6,7,8-tetrahydropteridin-4-one + O2
?
show the reaction diagram
-
-
-
-
?
(RS)-batyl alcohol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
1-alkyl-sn-glycerol + tetrahydrobiopterin + O2
1-hydroxyalkyl-sn-glycerol + dihydrobiopterin + H2O
show the reaction diagram
1-alkyl-sn-glycerol + tetrahydrobiopterin + O2
1-O-alkyl-sn-glycerol + dihydrobiopterin + H2O
show the reaction diagram
1-O-alkyl-2-lyso-sn-glycero-3-phosphocholine + tetrahydrobiopterin + O2
glycerophosphocholine + alkylaldehyde + dihydrobiopterin + H2O
show the reaction diagram
-
1-O-alkyl-2-lyso-sn-glycero-3-phosphocholine is lyso-platelet activating factor
-
-
?
1-O-alkyl-sn-glycerol + tetrahydrobiopterin + O2
1-O-(1-hydroxyalkyl)-sn-glycerol + dihydrobiopterin + H2O
show the reaction diagram
-
-
-
-
?
1-O-alkyl-sn-glycerol 3-phosphate + tetrahydrobiopterin + O2
1-O-(1-hydroxyalkyl)-sn-glycerol 3-phosphate + 6,7-[8]-dihydrobiopterin + H2O
show the reaction diagram
1-O-hexadecyl-sn-glycero-3-phosphocholine + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
1-O-hexadecylglycerol + tetrahydrobiopterin + O2
1-O-(1-hydroxy-hexadecyl)-sn-glycerol + dihydrobiopterin + H2O
show the reaction diagram
-
-
-
-
r
1-O-pyrenedecyl-glycerol + tetrahydrobiopterin + O2
?
show the reaction diagram
1-O-pyrenedecyl-sn-glycerol + tetrahydrobiopterin + O2
1-hydroxypyrenedecyl-sn-glycerol + dihydrobiopterin + H2O
show the reaction diagram
-
1-O-pyrenedecyl-sn-glycerol and high-performance liquid chromatographic analysis of reaction mixtures with fluorescence detection, overview
further formation of 1-pyrenedecanoic acid
-
?
1-O-pyrenedecyl-sn-glycerol + tetrahydrobiopterin + O2
?
show the reaction diagram
-
activity assay
-
-
?
1-O-pyrenedecyl-sn-glycerol + tetrahydrobiopterin + O2
? + dihydrobiopterin + H2O
show the reaction diagram
-
-
-
-
?
1-O-pyrenedecyl-sn-glycerol + tetrahydrobiopterin + O2
glycerol + pyrenedecanal + 6,7[8H]-dihydrobiopterin + H2O
show the reaction diagram
-
-
-
-
?
1-O-pyrenenonyl-sn-glycerol + tetrahydrobiopterin + O2
?
show the reaction diagram
-
activity assay
-
-
?
2-(1-hexadecyloxy)propan-1,3-diol + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
2-(1-octadecyloxy)ethanol + RS-(cis)-6,7-dimethyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
2-(1-octadecyloxy)ethanol + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
2-1'-n-hexadecyloxyethanol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
2-1'-n-octadecyloxyethanol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
2-hexadecyloxy-ethan-1-ol + 5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
2-hexadecyloxy-ethan-1-ol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
2-hexadecyloxyethan-1-ol + 5,6,7,8-tetrahydrofolic acid + O2
?
show the reaction diagram
-
-
-
-
?
2-hexadecyloxyethan-1-ol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
2-hexadecyloxyethan-1-ol + 6R-tetrahydrobiopterin + O2
?
show the reaction diagram
-
-
-
-
?
2-hexadecyloxypropane-1,3-diol + 6-methyl-5,6,7,8-tetrahydropterin
?
show the reaction diagram
-
-
-
-
?
2-hexadecylthioethan-1-ol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
2-octadecyloxyethan-1-ol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
2-octadecylthioethan-ol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
3-(1-octadecylthio)propan-1,2-diol + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
3-1'-hexadecyloxy-2-methoxy-propan-1-ol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
3-1'-hexadecyloxy-2-methoxy-propan-2-ol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
3-1'-n-hexadecylthiopropane-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
3-1'-n-octadecylthiopropane-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
3-hexadecyloxy-1-methoxypropan-1-ol + 6-methyl-5,6,7,8-tetrahydropterin
?
show the reaction diagram
-
-
-
-
?
3-hexadecyloxy-2-methoxypropan-1-ol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
3-O-hexadecyl glycerol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
alkylglycerol + tetrahydrobiopterin + O2
glycerol + fatty aldehyde + 6,7[8H]-dihydrobiopterin + H2O
show the reaction diagram
-
-
after rapid decay of the resulting unstable primary product (hemiacetal)
-
?
batyl alcohol + 6R-5,6,7,8-tetrahydrobiopterin + O2
?
show the reaction diagram
-
i.e. RS-3-(1-octadecyloxy)propan-1,2-doiol
-
-
?
batyl alcohol + 6R-tetrahydrobiopterin + O2
?
show the reaction diagram
-
-
-
-
?
batyl alcohol + RS-(cis)-6,7-dimethyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
i.e. RS-3-(1-octadecyloxy)propan-1,2-diol
-
-
?
cis-RS-3-octadec-9'-enyloxypropane-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
hexadecyl glycerol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
hexadecylglycerol + tetrahydrobiopterin + O2
?
show the reaction diagram
hexadecylglycerol + tetrahydrobiopterin + O2
hexadecanal + glycerol + dihydrobiopterin + H2O
show the reaction diagram
lyso-alkyl-glycerol phospholipid + tetrahydrobiopterin + O2
1-O-(1-hydroxyalkyl)-sn-glycerol + 6,7-[8]-dihydrobiopterin + H2O
show the reaction diagram
-
-
-
-
?
lyso-platelet activating factor + tetrahydrobiopterin + O2
?
show the reaction diagram
octadecylglycerol + tetrahydrobiopterin + O2
?
show the reaction diagram
prodigiosin + tetrahydrobiopterin + O2
cycloprodigiosin + dihydrobiopterin + H2O
show the reaction diagram
-
-
-
-
?
R-3-(1-octadecyloxy)propan-1,2-diol + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
R-3-dodecyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
R-3-eicosanyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
R-3-heneicosanyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
R-3-heptadecyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
R-3-hexadecyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
R-3-nonadecyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
R-3-nonadecyloxypropane-1,2-diol + tetrahydrobiopterin + O2
?
show the reaction diagram
-
-
-
-
r
R-3-octadecyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
R-3-pentadecyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
R-3-tridecyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
R-3-undecyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-(1-heptyloxy)propan-1,2-diol + RS-6-methyl-5,6,7,8-tetrahydropterin
?
show the reaction diagram
-
-
-
-
?
RS-3-(1-hexadecyloxy)-1-methoxypropan-2-ol + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-(1-hexadecyloxy)-2-hydroxypropane-1-phosphocholine + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-(1-hexadecyloxy)propan-1,2-diol + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-(1-hexadecyloxy)propan-1-ol + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-(1-oleyloxy)propan-1,2-diol + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-docosanyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-dodecyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-heptyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-hexyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-nonyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-octyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-pentyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-propyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-3-tetradecyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-cyclohexylmethoxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-hexadecylthiopropane-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
RS-octadecylthiopropane-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
S-3-(1-hexadecyloxy)-2-hydroxypropane-1-phosphocholine + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
S-3-(1-octadecyloxy)propan-1,2-diol + RS-6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
S-3-hexadecyloxypropane-1,2-diol + tetrahydrobiopterin + O2
?
show the reaction diagram
-
-
-
-
r
S-3-octadecyloxypropan-1,2-diol + 6-methyl-5,6,7,8-tetrahydropterin + O2
?
show the reaction diagram
-
-
-
-
?
additional information
?
-