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1.14.14.59: dimethylnonatriene synthase

This is an abbreviated version!
For detailed information about dimethylnonatriene synthase, go to the full flat file.

Reaction

(3S,6E)-nerolidol
+
[reduced NADPH-hemoprotein reductase]
+
O2
=
(3E)-4,8-dimethylnona-1,3,7-triene
+
[oxidized NADPH-hemoprotein reductase]
+
but-3-en-2-one
+ 2 H2O

Synonyms

At3g25180, CYP82G1, CYP92C5, DMNT/TMTT homoterpene synthase

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.14.59 dimethylnonatriene synthase

Crystallization

Crystallization on EC 1.14.14.59 - dimethylnonatriene synthase

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CRYSTALLIZATION (Commentary)
ORGANISM
UNIPROT
LITERATURE
modeling and substrate docking support an oxidative bond cleavage of the alcohol substrate via syn-elimination of the polar head, together with an allylic C-5 hydrogen atom