1.14.14.52: (S)-limonene 7-monooxygenase
This is an abbreviated version!
For detailed information about (S)-limonene 7-monooxygenase, go to the full flat file.
Reaction
Synonyms
(-)-limonene 7-monooxygenase, (-)-limonene hydroxylase, (-)-limonene,NADPH:oxygen oxidoreductase (7-hydroxylating, (-)-limonene-7-hydroxylase, EC 1.14.13.49, More, oxygenase, (-)-limonene mono-
ECTree
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Substrates Products
Substrates Products on EC 1.14.14.52 - (S)-limonene 7-monooxygenase
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REACTION DIAGRAM
(+)-limonene + NADPH + O2
perillyl alcohol + NADP+ + H2O
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hydroxylation at the same rate as (-)-limonene
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(S)-limonene + NADPH + H+ + O2
(-)-perillyl alcohol + NADP+ + H2O
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(-)-(S)-limonene + NADPH + O2
(-)-perillyl alcohol + NADP+ + H2O
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perillyl alcohol + NADP+ + H2O
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highly specific
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(-)-limonene + NADPH + O2
perillyl alcohol + NADP+ + H2O
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one of the key reactions of oxygenated monoterpenes, perillyl aldehyde biosynthesis
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no substrates: isolimonenes, terpinolene, alpha- or beta-phellandrene, alpha- or beta-terpinene, bicyclic monoterpenes: pinene, sabinene, alpha-thujene, p-cymene, cis- or trans-p-menthane, p-menth-1-ene, i.e. 8,9-dihydrolimonene
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additional information
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the kinetically competent recombinant protein produces a mixture of C3-, C6- and C7-hydroxylated limonene derivatives, i.e. (-)-perillyl alcohol, (-)-trans-isopiperitenol, and (-)-trans-carveol, with a distribution of 33%, 14% and 53%, respectively, thus it performs the reaction of EC 1.14.13.47 and 1.14.13.48, overview
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