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1.14.14.51: (S)-limonene 6-monooxygenase

This is an abbreviated version!
For detailed information about (S)-limonene 6-monooxygenase, go to the full flat file.

Word Map on EC 1.14.14.51

Reaction

(S)-limonene
+
[reduced NADPH-hemoprotein reductase]
+
O2
=
(-)-trans-carveol
+
[oxidized NADPH-hemoprotein reductase]
+
H2O

Synonyms

(+)-limonene-6-hydroxylase, (-)-(4S)-limonene-6-hydroxylase, (-)-limonene 6-hydroxylase, (-)-limonene 6-monooxygenase, (-)-limonene,NADPH:oxygen oxidoreductase (6-hydroxylating), (-)-limonene-6-hydroxylase, 4S-limonene-6-hydroxylase, EC 1.14.13.48, limonene hydroxylase, limonene-6-hydroxylase, oxygenase, (-)-limonene 6-mono-

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.14.51 (S)-limonene 6-monooxygenase

Substrates Products

Substrates Products on EC 1.14.14.51 - (S)-limonene 6-monooxygenase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(+)-limonene + NADPH + O2
(+)-cis-carveol + NADP+ + H2O
show the reaction diagram
(+)-p-menth-1-ene + NADPH + O2
(+)-cis-carvotanacetol + NADP+ + H2O
show the reaction diagram
(-)-(4S)-limonene + NADPH + O2
(-)-(4R,6S)-trans-carveol + NADP+ + H2O
show the reaction diagram
(-)-(4S)-limonene + NADPH + O2
(-)-trans-isopiperitenol + NADP+ + H2O
show the reaction diagram
-
mutant F363I
mutant F363I
?
(-)-(S)-limonene + NADPH + O2
(-)-trans-carveol + NADP+
show the reaction diagram
(-)-limonene + NADPH + O2
(-)-trans-carveol + NADP+ + H2O
show the reaction diagram
-
one of the key reactions of oxygenated monoterpenes, biosynthesis of (-)-carvone
-
-
?
(-)-p-menth-1-ene + NADPH + O2
(-)-trans-carvotanacetol + NADP+ + H2O
show the reaction diagram
(S)-limonene + NADPH + H+ + O2
(-)-trans-carveol + NADP+ + H2O
show the reaction diagram
(S)-limonene + [reduced NADH-hemoprotein reductase] + O2
(-)-trans-carveol + [oxidized NADH-hemoprotein reductase] + H2O
show the reaction diagram
(S)-limonene + [reduced NADPH-hemoprotein reductase] + O2
(-)-trans-carveol + [oxidized NADPH-hemoprotein reductase] + H2O
show the reaction diagram
-
-
-
-
?
1-cyclohexene 1-methanol + NAD+
1-cyclohexen-1-carbaldehyde + NADH + H+
show the reaction diagram
4-isopropyl benzyl alcohol + NAD+
4-isopropylbenzyl aldehyde + NADH
show the reaction diagram
4-methyl benzyl alcohol + NAD+
? + NADH
show the reaction diagram
17.1% activity compared to perillyl alcohol
-
-
?
benzyl alcohol + NAD+
benzaldehyde + NADH
show the reaction diagram
carveol + NAD+
? + NADH
show the reaction diagram
86% activity compared to perillyl alcohol
-
-
?
cyclohexyl methanol + NAD+
cyclohexylaldehyde + NADH
show the reaction diagram
15.8% activity compared to perillyl alcohol
-
-
?
myrtenol + NAD+
myrtenal + NADH
show the reaction diagram
4.0% activity compared to perillyl alcohol
-
-
?
perillyl alcohol + NAD+
perillyl aldehyde + NADH
show the reaction diagram
perillyl aldehyde + NADH
perillyl alcohol + NAD+
show the reaction diagram
-
-
-
r
additional information
?
-