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1.14.14.42: homomethionine N-monooxygenase

This is an abbreviated version!
For detailed information about homomethionine N-monooxygenase, go to the full flat file.

Word Map on EC 1.14.14.42

Reaction

an L-N,N-dihydroxypolyhomomethionine
=
an (E)-omega-(methylsulfanyl)alkanal oxime
+
CO2
+
H2O

Synonyms

CYP79F1, CYP79F2, dihomomethionine N-hydroxylase, hexahomomethionine N-hydroxylase

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.14.42 homomethionine N-monooxygenase

Substrates Products

Substrates Products on EC 1.14.14.42 - homomethionine N-monooxygenase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
L-dihomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
4-methylthiopentanaldoxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
show the reaction diagram
-
-
-
?
L-dihomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
omega-(methylthio)-(E)-pentanaldehyde oxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
show the reaction diagram
-
overall reaction, product is the precursor of the major glucosinolates in leaves of Arabidopsis thaliana
-
?
L-hexahomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
4-methylthiononanaldoxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
show the reaction diagram
-
overall reaction
-
?
L-homomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
4-methylthiobutanaldoxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
show the reaction diagram
-
-
-
?
L-pentahomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
4-methylthiooctanaldoxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
show the reaction diagram
-
overall reaction
-
?
L-tetrahomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
4-methylthioheptanaldoxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
show the reaction diagram
-
overall reaction
-
?
L-trihomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
4-methylthiohexanaldoxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
show the reaction diagram
-
overall reaction
-
?
L-trihomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
omega-(methylthio)-(E)-hexanaldehyde oxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
show the reaction diagram
-
overall reaction
-
?
additional information
?
-