1.14.14.42: homomethionine N-monooxygenase
This is an abbreviated version!
For detailed information about homomethionine N-monooxygenase, go to the full flat file.
Word Map on EC 1.14.14.42
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1.14.14.42
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glucosinolates
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cyp83a1
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brassica
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glucoraphanin
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cabbage
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auxin
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ugt74b1
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oleraceae
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broccoli
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methionine-derived
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gluconapin
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sulforaphane
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brassicales
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brassicaceae
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silique
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chain-elongated
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oximes
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aldoximes
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sinigrin
- 1.14.14.42
- glucosinolates
- cyp83a1
- brassica
- glucoraphanin
- cabbage
- auxin
-
ugt74b1
-
oleraceae
- broccoli
-
methionine-derived
- gluconapin
- sulforaphane
- brassicales
- brassicaceae
- silique
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chain-elongated
- oximes
- aldoximes
- sinigrin
Reaction
Synonyms
CYP79F1, CYP79F2, dihomomethionine N-hydroxylase, hexahomomethionine N-hydroxylase
ECTree
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Natural Substrates Products
Natural Substrates Products on EC 1.14.14.42 - homomethionine N-monooxygenase
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REACTION DIAGRAM
L-dihomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
4-methylthiopentanaldoxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
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-
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?
L-dihomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
omega-(methylthio)-(E)-pentanaldehyde oxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
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overall reaction, product is the precursor of the major glucosinolates in leaves of Arabidopsis thaliana
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?
L-hexahomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
4-methylthiononanaldoxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
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overall reaction
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?
L-homomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
4-methylthiobutanaldoxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
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-
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?
L-pentahomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
4-methylthiooctanaldoxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
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overall reaction
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?
L-tetrahomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
4-methylthioheptanaldoxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
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overall reaction
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?
L-trihomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
4-methylthiohexanaldoxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
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overall reaction
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?
L-trihomomethionine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
omega-(methylthio)-(E)-hexanaldehyde oxime + CO2 + 3 H2O + 2 [oxidized NADPH-hemoprotein reductase]
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overall reaction
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?
?
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isoform CYP79F1 metabolizes mono- to hexahomomethionine, resulting in both short- and long-chain aliphatic glucosinolates. No substrates: phenylalanine,homophenylalanine, tyrosine, tryptophan, and methionine
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?
additional information
?
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isoform CYP79F1 metabolizes mono- to hexahomomethionine, resulting in both short- and long-chain aliphatic glucosinolates. No substrates: phenylalanine,homophenylalanine, tyrosine, tryptophan, and methionine
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-
?
additional information
?
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isoform CYP79F1 metabolizes mono- to hexahomomethionine, resulting in both short- and long-chain aliphatic glucosinolates. No substrates: phenylalanine,homophenylalanine, tyrosine, tryptophan, and methionine
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-
?
additional information
?
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isoform CYP79F2 exclusively metabolizes long-chain elongated penta- and hexahomomethionines. No substrates: phenylalanine, homophenylalanine, tyrosine, tryptophan, and methionine
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?
additional information
?
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isoform CYP79F2 exclusively metabolizes long-chain elongated penta- and hexahomomethionines. No substrates: phenylalanine, homophenylalanine, tyrosine, tryptophan, and methionine
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-
?
additional information
?
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isoform CYP79F2 exclusively metabolizes long-chain elongated penta- and hexahomomethionines. No substrates: phenylalanine, homophenylalanine, tyrosine, tryptophan, and methionine
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-
?