L-evernosamine nitrososynthase

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For detailed information about L-evernosamine nitrososynthase, go to the full flat file.

Word Map on EC


+ 2 NADPH + 2 H+ + 2 O2 =
+ 2 NADP+ + 3 H2O


DnmZ, nitrososynthase, ORF36


     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.13 With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
       L-evernosamine nitrososynthase

Systematic Name

Systematic Name on EC - L-evernosamine nitrososynthase

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IUBMB Comments
dTDP-beta-L-evernosamine,NADPH:oxygen oxidoreductase (N-hydroxylating)
Requires FAD. Isolated from the bacterium Micromonospora carbonacea var. africana. The nitroso group is probably spontaneously oxidized to a nitro group giving dTDP-beta-L-evernitrose, which is involved in the biosynthesis of the antibiotic everninomycin. The reaction was studied using dTDP-beta-L-4-epi-vancosamine (dTDP-4-O-desmethyl-beta-L-evernitrosamine).