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1.14.13.170: pentalenolactone D synthase

This is an abbreviated version!
For detailed information about pentalenolactone D synthase, go to the full flat file.

Reaction

1-deoxy-11-oxopentalenate
+
NADPH
+
H+
+
O2
=
pentalenolactone D
+
NADP+
+
H2O

Synonyms

Baeyer-Villiger monooxygenase, penE, pntE

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.13 With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.13.170 pentalenolactone D synthase

Systematic Name

Systematic Name on EC 1.14.13.170 - pentalenolactone D synthase

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SYSTEMATIC NAME
IUBMB Comments
1-deoxy-11-oxopentalenate,NADH:oxygen oxidoreductase (pentalenolactone-D forming)
A FAD-dependent oxygenase. Isolated from the bacteria Streptomyces exfoliatus and Streptomyces arenae. The ketone undergoes a biological Baeyer-Villiger reaction. Part of the pathway of pentalenolactone biosynthesis.