1.14.13.105: monocyclic monoterpene ketone monooxygenase
This is an abbreviated version!
For detailed information about monocyclic monoterpene ketone monooxygenase, go to the full flat file.
Reaction
Synonyms
Baeyer-Villiger mono-oxygenase, Baeyer-Villiger monooxygenase, BVMO, dihydrocarvone 1,2-monooxygenase, MMKMO, monocyclic monoterpene ketone mono-oxygenase, NADPH-dependent 1-hydroxy-2-oxolimonene 1,2-monooxygenase, NADPH-dependent dihydrocarvone monooxygenase
ECTree
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Reaction
Reaction on EC 1.14.13.105 - monocyclic monoterpene ketone monooxygenase
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1-hydroxymenth-8-en-2-one + NADPH + H+ + O2 = 7-hydroxy-4-isopropenyl-7-methyloxepan-2-one + NADP+ + H2O
followed by the spontaneous reaction of 7-hydroxy-4-isopropenyl-7-methyloxepan-2-one = 3-isopropenyl-6-oxoheptanoate
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