1.14.12.26: chlorobenzene dioxygenase
This is an abbreviated version!
For detailed information about chlorobenzene dioxygenase, go to the full flat file.
Word Map on EC 1.14.12.26
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1.14.12.26
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toluene
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dihydrodiols
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putida
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chlorocatechol
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burkholderia
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ralstonia
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alpha-subunits
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biphenyls
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catechols
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chlorinated
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dioxygenation
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1,2-dioxygenase
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1,2,4,5-tetrachlorobenzene
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1,2,4-trichlorobenzene
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naphthalene
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dichlorobenzenes
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biosurfactant
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chloromuconate
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meta-cleavage
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dehalogenation
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3-chlorobenzoate
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cycloisomerase
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synthesis
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dioxygenolytic
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chloroaromatic
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3-oxoadipate
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1,3-dichlorobenzene
- 1.14.12.26
- toluene
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dihydrodiols
- putida
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chlorocatechol
- burkholderia
- ralstonia
- alpha-subunits
- biphenyls
- catechols
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chlorinated
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dioxygenation
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1,2-dioxygenase
- 1,2,4,5-tetrachlorobenzene
- 1,2,4-trichlorobenzene
- naphthalene
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dichlorobenzenes
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biosurfactant
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chloromuconate
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meta-cleavage
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dehalogenation
- 3-chlorobenzoate
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cycloisomerase
- synthesis
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dioxygenolytic
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chloroaromatic
- 3-oxoadipate
- 1,3-dichlorobenzene
Reaction
Synonyms
CDO, TecA, tetrachlorobenzene dioxygenase
ECTree
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Substrates Products
Substrates Products on EC 1.14.12.26 - chlorobenzene dioxygenase
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REACTION DIAGRAM
1,4-dimethylbenzene + NADH + H+ + O2
? + NAD+
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oxidized with low efficiency
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-
?
2,3-dichlorotoluene + NADH + H+ + O2
2,3-dichlorobenzyl alcohol + NAD+
-
-
-
-
?
2,4,5-trichlorotoluene + NADH + H+ + O2
2,4,5-trichlorobenzyl alcohol + NAD+
-
-
-
-
?
2,6-dichlorotoluene + NADH + H+ + O2
2,6-dichlorobenzyl alcohol + NAD+
-
-
-
-
?
2-bromobenzonitrile + NADH + H+ + O2
cis-1,2-dihydroxy-3-cyanocyclohexa-4-bromo-3,5-diene + NAD+
Q52383; Q52384; Q52385; Q52386
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-
-
?
2-chlorobenzonitrile + NADH + H+ + O2
cis-1,2-dihydroxy-3-cyanocyclohexa-4-chloro-3,5-diene + NAD+
Q52383; Q52384; Q52385; Q52386
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-
-
?
2-fluorobenzonitrile + NADH + H+ + O2
cis-1,2-dihydroxy-3-cyanocyclohexa-4-fluoro-3,5-diene + NAD+
Q52383; Q52384; Q52385; Q52386
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-
-
?
3,5-dichlorotoluene + NADH + H+ + O2
3,5-dichlorobenzyl alcohol + NAD+
-
-
-
-
?
3-fluorobenzonitrile + NADH + H+ + O2
cis-1,2-dihydroxy-3-cyanocyclohexa-5-fluoro-3,5-diene + NAD+
Q52383; Q52384; Q52385; Q52386
-
-
-
?
4-chlorobenzonitrile + NADH + H+ + O2
cis-1,2-dihydroxy-3-cyanocyclohexa-6-chloro-3,5-diene + NAD+
Q52383; Q52384; Q52385; Q52386
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-
-
?
4-fluorobenzonitrile + NADH + H+ + O2
cis-1,2-dihydroxy-3-cyanocyclohexa-6-fluoro-3,5-diene + NAD+
Q52383; Q52384; Q52385; Q52386
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-
-
?
4-methylbenzonitrile + NADH + H+ + O2
cis-1,2-dihydroxy-3-cyanocyclohexa-6-methyl-3,5-diene + NAD+
Q52383; Q52384; Q52385; Q52386
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-
-
?
benzonitrile + NADH + H+ + O2
cis-1,2-dihydroxy-3-cyanocyclohexa-3,5-diene + NAD+
Q52383; Q52384; Q52385; Q52386
-
-
-
?
benzyl cyanide + NADH + H+ + O2
cis-1,2-dihydroxy-3,5-cyclohexadienyl acetonitrile + NAD+
Q52383; Q52384; Q52385; Q52386
-
-
-
?
cinnamonitrile + NADH + H+ + O2
trans-3-[(5S,6R)-5,6-dihydroxycyclo-hexa-1,3-dienyl]-acrylonitrile + NAD+
Q52383; Q52384; Q52385; Q52386
-
-
-
?
cinnamonitrile + NADH + H+ + O2
trans-3-[(5S,6R)-5,6-dihydroxycyclohexa-1,3-dienyl]-acrylonitrile + NAD+
Q52383; Q52384; Q52385; Q52386
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-
-
?
methylbenzene + NADH + H+ + O2
? + NAD+
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oxidized with low efficiency
-
-
?
? + NAD+
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the enzyme dioxygenolytically attacks a chlorosubstituted carbon atom of Cl4-benzene, thereby forming an unstable diol intermediate which spontaneously rearomatizes with concomitant chloride elimination to the corresponding 3,4,6-trichlorocatechol (Cl3-catechol)
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-
?
(1R,2R)-3-chlorocyclohexa-3,5-diene-1,2-diol + NAD+
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-
-
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?
chlorobenzene + NADH + H+ + O2
(1R,2R)-3-chlorocyclohexa-3,5-diene-1,2-diol + NAD+
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-
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?