1.14.11.43: (S)-dichlorprop dioxygenase (2-oxoglutarate)
This is an abbreviated version!
For detailed information about (S)-dichlorprop dioxygenase (2-oxoglutarate), go to the full flat file.
Reaction
Synonyms
(S)-phenoxypropionate/alpha-ketoglutarate-dioxygenase, 2-oxoglutarate-dependent (S)-dichlorprop dioxygenase, alpha-ketoglutarate-dependent (S)-dichlorprop dioxygenase, SdpA
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Natural Substrates Products
Natural Substrates Products on EC 1.14.11.43 - (S)-dichlorprop dioxygenase (2-oxoglutarate)
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REACTION DIAGRAM
(R)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2
2,4-dichlorophenol + pyruvate + succinate + CO2
i.e. (S)-dichlorprop, the enzyme is involved in the degradation of phenoxyalkanoic acid herbicides in Sphingomonas herbicidovorans MH. SdpA activity is completely absent in the absence of 2-oxoglutarate
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(R)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2
2-methyl-4-chlorophenol + pyruvate + succinate + CO2
i.e. (S)-mecoprop, the enzyme is involved in the degradation of phenoxyalkanoic acid herbicides in Sphingomonas herbicidovorans MH. SdpA activity is completely absent in the absence of 2-oxoglutarate
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?
(S)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2
2,4-dichlorophenol + pyruvate + succinate + CO2
(S)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2
4-chloro-2-methylphenol + pyruvate + succinate + CO2
2,4-dichlorophenol + pyruvate + succinate + CO2
i.e. (S)-dichlorprop, the enzyme is involved in degrading the chiral herbicides (RS)-2-(2,4-dichlorophenoxy)propionate (dichlorprop) and (RS)-2-(4-chloro-2-methylphenoxy)propionate (mecoprop). SdpA is highly specific for the cleavage of the S-configuration of dichlorprop and mecoprop
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?
(S)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2
2,4-dichlorophenol + pyruvate + succinate + CO2
i.e. (S)-dichlorprop, the enzyme is involved in degrading the chiral herbicides (RS)-2-(2,4-dichlorophenoxy)propionate (dichlorprop) and (RS)-2-(4-chloro-2-methylphenoxy)propionate (mecoprop). SdpA is highly specific for the cleavage of the S-configuration of dichlorprop and mecoprop
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?
(S)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2
2,4-dichlorophenol + pyruvate + succinate + CO2
the enzyme catalyzes the initial step of microbial degradation of the chiral herbicide (R,S)-2-(2,4-dichlorophenoxy)propionate (R,S-dichlorprop)
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4-chloro-2-methylphenol + pyruvate + succinate + CO2
i.e. (S)-mecoprop, the enzyme is involved in degrading the chiral herbicides (RS)-2-(2,4-dichlorophenoxy)propionate (dichlorprop) and (RS)-2-(4-chloro-2-methylphenoxy)propionate (mecoprop). SdpA is highly specific for the cleavage of the S-configuration of dichlorprop and mecoprop
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-
?
(S)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2
4-chloro-2-methylphenol + pyruvate + succinate + CO2
i.e. (S)-mecoprop, the enzyme is involved in degrading the chiral herbicides (RS)-2-(2,4-dichlorophenoxy)propionate (dichlorprop) and (RS)-2-(4-chloro-2-methylphenoxy)propionate (mecoprop). SdpA is highly specific for the cleavage of the S-configuration of dichlorprop and mecoprop
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-
?