1.13.12.21: tetracenomycin-F1 monooxygenase
This is an abbreviated version!
For detailed information about tetracenomycin-F1 monooxygenase, go to the full flat file.
Reaction
Synonyms
TcmF1 monooxygenase, TmcH
ECTree
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Substrates Products
Substrates Products on EC 1.13.12.21 - tetracenomycin-F1 monooxygenase
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REACTION DIAGRAM
tetracenomycin D3 + H2O
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the enzyme is involved in the biosynthesis of tetracenomycin C
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tetracenomycin F1 + O2
tetracenomycin D3 + H2O
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i.e. 3,8,10,12-tetrahydroxy-1-methyl-6,11-dioxo-6,11-dihydrotetracene-2-carboxylate = 6,11-dihydro-3,8,10,12-tetrahydroxy-1-methyl-6,11-dioxo-2-naphthacenecarboxylic acid
i.e. 3,8,10,12-tetrahydroxy-1-methyl-11-oxo-6,11-dihydro-2-tetracenecarboxylate, i.e. 6,11-dihydro-3,8,10,12-tetrahydroxy-1-methyl-11-oxo-2-naphthacenecarboxylic acid
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