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1.13.11.B6: linoleate 9/13-lipoxygenase

This is an abbreviated version!
For detailed information about linoleate 9/13-lipoxygenase, go to the full flat file.

Word Map on EC 1.13.11.B6

Reaction

2 linoleate + 2 O2 =

(10E,12Z)-9-hydroperoxy-10,12-octadecadienoate
+
(9Z,11E)-13-hydroperoxy-9,11-octadecadienoate

Synonyms

13/9 lipoxygenase, 13/9-LOX, 9-/13-LOXN2, 9-lipoxygenase, 9-LOX, 9/13-lipoxygenase, 9/13-LOX, Ca-LOC-1, dual positional specific LOX, linoleate 9 S-lipoxygenase, linoleate oxygen oxidoreductase, linolenate 9R-dioxygenase, lipoxygenase, LOX, lox1-St-2, LOX1-Zm1, LOX1:Md:1a, LOX1a, LOX2:Md:2a, LOX2a, manganese 9S-lipoxygenase, MoLOX1, OsLOX1, PnLOX1, S-LOX

ECTree

     1 Oxidoreductases
         1.13 Acting on single donors with incorporation of molecular oxygen (oxygenases)
             1.13.11 With incorporation of two atoms of oxygen
                1.13.11.B6 linoleate 9/13-lipoxygenase

Natural Substrates Products

Natural Substrates Products on EC 1.13.11.B6 - linoleate 9/13-lipoxygenase

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NATURAL SUBSTRATE
NATURAL PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
(9Z,12Z)-octadeca-9,12-dienoic acid + O2
(12Z)-9-hydroxy-10-oxo-12-octadecenoic acid
show the reaction diagram
(9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + O2
(9R,10E,12Z,15Z)-9-hydroperoxyoctadeca-10,12,15-trienoic acid + (9Z,12Z,15Z)-9-hydroxy-10-oxooctadeca-12,15-dienoic acid
show the reaction diagram
all-cis-9,12,15-octadecatrienoic acid + O2
(9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid + 9-hydroxy-10-oxo-(12Z,15Z)-octadecadienoic acid
show the reaction diagram
all-cis-9,12-octadecadienoic acid + O2
9-hydroxy-10-oxo-12Z-octadecenoic acid
show the reaction diagram
-
i.e. linoleic acid
the alpha-ketol is the main metabolite formed from 9R-hydroperoxyoctadecadienoic acid
-
?
linoleate + O2
(9R,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate + (9Z,11E,13R)-13-hydroperoxy-9,11-octadecadienoate
show the reaction diagram
-
-
-
?
linoleate + O2
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate
show the reaction diagram
-
-
-
?
linoleate + O2
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate + (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate
show the reaction diagram
-
the ratio of (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate to (9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate is 4:3
-
?
linoleate + O2
(9Z,11E,13S)-13-hydroperoxyoctadeca-9,11-dienoate
show the reaction diagram
-
-
-
?
linoleate + O2
9-hydroperoxy-10,12-octadecadienoate + 13-hydroperoxy-9,11-octadecadienoate
show the reaction diagram
-
-
-
?
linolenate + O2
?
show the reaction diagram
-
-
-
?
additional information
?
-