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1.13.11.83: 4-hydroxy-3-prenylphenylpyruvate oxygenase

This is an abbreviated version!
For detailed information about 4-hydroxy-3-prenylphenylpyruvate oxygenase, go to the full flat file.

Reaction

3-dimethylallyl-4-hydroxyphenylpyruvate
+
O2
=
3-dimethylallyl-4-hydroxymandelate
+
CO2

Synonyms

CloR

ECTree

     1 Oxidoreductases
         1.13 Acting on single donors with incorporation of molecular oxygen (oxygenases)
             1.13.11 With incorporation of two atoms of oxygen
                1.13.11.83 4-hydroxy-3-prenylphenylpyruvate oxygenase

Systematic Name

Systematic Name on EC 1.13.11.83 - 4-hydroxy-3-prenylphenylpyruvate oxygenase

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SYSTEMATIC NAME
IUBMB Comments
3-dimethylallyl-4-hydroxyphenylpyruvate:oxygen 1,2-oxidoreductase (3-dimethylallyl-4-hydroxymandelate forming)
Requires non-heme-iron(II). Isolated from the bacterium Streptomyces roseochromogenes DS 12976. A bifunctional enzyme involved in clorobiocin biosynthesis that also catalyses the activity of EC 1.13.12.23, 4-hydroxy-3-prenylbenzoate synthase.