1.13.11.50: acetylacetone-cleaving enzyme

This is an abbreviated version, for detailed information about acetylacetone-cleaving enzyme, go to the full flat file.

Reaction

Pentane-2,4-dione
+
O2
=
acetate
+
methylglyoxal

Synonyms

acetylacetone dioxygenase, acetylacetone-cleaving enzyme, b-diketone dioxygenase, cupin-type dioxygenase, diketone cleaving dioxygenase, diketone cleaving enzyme, diketone dioxygenase, diketone-cleaving dioxygenase, diketone-cleaving enzyme, Dke1, oxygenase, b-diketone di-, pentane-2,4-dione hydrolase

ECTree

     1 Oxidoreductases
         1.13 Acting on single donors with incorporation of molecular oxygen (oxygenases)
             1.13.11 With incorporation of two atoms of oxygen
                1.13.11.50 acetylacetone-cleaving enzyme

Substrates Products

Substrates Products on EC 1.13.11.50 - acetylacetone-cleaving enzyme

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
1,1,1-trifluoro-2,4-pentanedione + O2
?
show the reaction diagram
-
-
-
-
?
1,1,1-trifluoro-pentane-2,4-dione + O2
?
show the reaction diagram
1,1-difluoro-2,4-pentanedione + O2
?
show the reaction diagram
-
-
-
-
?
1,1-difluoropentane-2,4-dione + O2
?
show the reaction diagram
-
-
-
-
?
1-phenyl-1,3-butanedione + O2
?
show the reaction diagram
-
-
-
-
?
1-phenylbutane-1,3-dione + O2
?
show the reaction diagram
-
-
-
-
?
2,4-dioxopentanoic acid ethyl ester + O2
?
show the reaction diagram
2,4-nonadione + O2
?
show the reaction diagram
-
poor substrate
-
-
?
2,4-octanedione + O2
?
show the reaction diagram
-
-
-
-
?
2-acetylcyclohexanone + O2
?
show the reaction diagram
-
-
-
-
?
3,4-dihydroxyphenylacetate + O2
?
show the reaction diagram
-
-
-
?
3,5-heptanedione + O2
?
show the reaction diagram
-
-
-
-
?
3-methyl-2,4-pentanedione + O2
?
show the reaction diagram
-
-
-
-
?
3-oxobutanone + O2
?
show the reaction diagram
4,4-difluoro-1-phenyl-1,3-butanedione + O2
?
show the reaction diagram
-
-
-
-
?
4-hydroxy-4-methyl-2-pentanone + O2
?
show the reaction diagram
-
-
-
-
?
5,5-dimethylhexane-2,4-dione + O2
?
show the reaction diagram
-
poor substrate
-
-
?
acetylacetone + O2
acetate + 2-oxopentanal
show the reaction diagram
-
-
-
-
?
acetylcyclohexanone + O2
?
show the reaction diagram
-
poor substrate
-
-
?
ethylacetoacetate + O2
?
show the reaction diagram
-
-
-
-
?
pentane-2,4-dione + O2
acetate + 2-oxopropanal
show the reaction diagram
pentane-2,4-dione + O2
acetate + methylglyoxal
show the reaction diagram
-
-
-
-
?
pentane-2,4-dione + O2
methylglyoxal + acetate
show the reaction diagram
-
-
-
?
potassium oxalate + O2
?
show the reaction diagram
-
-
-
?
quercetin + O2
?
show the reaction diagram
-
-
-
?
additional information
?
-