1.13.11.50: acetylacetone-cleaving enzyme

This is an abbreviated version!
For detailed information about acetylacetone-cleaving enzyme, go to the full flat file.

Word Map on EC 1.13.11.50

1.13.11.50

facial

acinetobacter

johnsonii

nonheme

methylglyoxal

five-coordinate

o2-dependent

fe2+-dependent

dioxygen-dependent

six-coordinate

bidentate

uv-vis

ferrous

non-native

r-groups

enzyme-bound

enol

metal-binding

2-his-1-carboxylate

ironii

high-spin

environmental protection

Reaction

Synonyms

acetylacetone dioxygenase, acetylacetone-cleaving enzyme, b-diketone dioxygenase, beta-diketone dioxygenase, cupin-type dioxygenase, diketone cleaving dioxygenase, diketone cleaving enzyme, diketone dioxygenase, diketone-cleaving dioxygenase, diketone-cleaving enzyme, DKDO, Dke1, oxygenase, b-diketone di-, pentane-2,4-dione hydrolase

ECTree

1 Oxidoreductases

1.13 Acting on single donors with incorporation of molecular oxygen (oxygenases)

1.13.11 With incorporation of two atoms of oxygen

1.13.11.50 acetylacetone-cleaving enzyme

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Results	in table
14	AA Sequence
1	Application
1	CAS Registry Number
7	Cloned(Commentary)
1	Cofactor
2	Crystallization (Commentary)
3	General Information
1	General Stability
11	Inhibitors
15	KM Value [mM]
1	Localization
22	Metals/Ions
11	Molecular Weight [Da]
9	Natural Substrates/ Products (Substrates)
15	Organism
4	PDB ID
4	pH Optimum
2	pH Range
25	Protein Variants
6	Purification (Commentary)
4	Reaction
5	Reaction Type
15	Reference
2	Source Tissue
4	Specific Activity [micromol/min/mg]
45	Substrates and Products (Substrate)
6	Subunits
35	Synonyms
1	Systematic Name
3	Temperature Optimum [°C]
2	Temperature Stability [°C]
31	Turnover Number [1/s]

Natural Substrates Products

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Natural Substrates Products on EC 1.13.11.50 - acetylacetone-cleaving enzyme

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acetylacetone + O2

acetate + 2-oxopentanal

Acinetobacter johnsonii

711258

pentane-2,4-dione + O2

acetate + 2-oxopropanal

2 entries

pentane-2,4-dione + O2

acetate + methylglyoxal

Acinetobacter johnsonii

725198, 725553

pentane-2,4-dione + O2

methylglyoxal + acetate

Acinetobacter johnsonii

Q8GNT2

696107

additional information

Acinetobacter johnsonii

acetylacetone dioxygenase catalyzes the dioxygen-dependent degradation of beta-dicarbonyl compounds

725198