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1.13.11.39: biphenyl-2,3-diol 1,2-dioxygenase

This is an abbreviated version!
For detailed information about biphenyl-2,3-diol 1,2-dioxygenase, go to the full flat file.

Word Map on EC 1.13.11.39

Reaction

biphenyl-2,3-diol
+
O2
=
2-hydroxy-6-oxo-6-phenylhexa-2,4-dienoate

Synonyms

2'-aminobiphenyl-2,3-diol 1,2-dioxygenase, 2,3-DBDO, 2,3-DBPD, 2,3-DHBD, 2,3-DHBP dioxygenase, 2,3-dihydroxy-biphenyl 1,2-dioxygenase, 2,3-dihydroxybiphenyl 1,2-dioxygenase, 2,3-dihydroxybiphenyl dioxygenase, 2,3-dihydroxybiphenyl-1,2-dioxygenase, 2,3-dihydroxybiphenyl:oxygen 1,2 oxidoreductase, 2,3-diOH-biphenyl 1,2-dioxygenase, 2,3DHBD, 2-aminobiphenyl-2,3-diol-1,2-dioxygenase, 23 OHBP oxygenase, 3-phenylcatechol dioxygenase, biphenyl-2,3-diol dioxygenase, BPDO, BphC, BphC1, BphC1-BN6, BphC2, BphC2-BN6, BphC3, bphC5, BphCLA-4, BphC_JF8, BphC_LA-4, C23o, CarB, CarBaBb, DHB12O, DHBD, EtbC, manganese(II)-dependent 2,3-dihydroxybiphenyl 1,2-dioxygenase, RrbphCI

ECTree

     1 Oxidoreductases
         1.13 Acting on single donors with incorporation of molecular oxygen (oxygenases)
             1.13.11 With incorporation of two atoms of oxygen
                1.13.11.39 biphenyl-2,3-diol 1,2-dioxygenase

Systematic Name

Systematic Name on EC 1.13.11.39 - biphenyl-2,3-diol 1,2-dioxygenase

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SYSTEMATIC NAME
IUBMB Comments
biphenyl-2,3-diol:oxygen 1,2-oxidoreductase (decyclizing)
Contains Fe2+ or Mn2+ [3]. This enzyme participates in the degradation pathway of biphenyl and PCB (poly chlorinated biphenyls), and catalyses the first ring cleavage step by incorporating two oxygen atoms into the catechol ring formed by EC 1.3.1.56, cis-2,3-dihydrobiphenyl-2,3-diol dehydrogenase.The enzyme from the bacterium Burkholderia xenovorans LB400 can also process catechol, 3-methylcatechol, and 4-methylcatechol, but less efficiently [1]. The enzyme from the carbazole-degrader Pseudomonas resinovorans strain CA10 also accepts 2'-aminobiphenyl-2,3-diol [5]. The enzyme from Ralstonia sp. SBUG 290 can also accept 1,2-dihydroxydibenzofuran and 1,2-dihydroxynaphthalene [4]. The enzyme is strongly inhibited by the substrate [1].Not identical with EC 1.13.11.2 catechol 2,3-dioxygenase.