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1.11.2.3: plant seed peroxygenase

This is an abbreviated version!
For detailed information about plant seed peroxygenase, go to the full flat file.

Word Map on EC 1.11.2.3

Reaction

R1H
+
R2OOH
=
R1OH
+
R2OH

Synonyms

9-hydroperoxide fatty acid reductase, caleosin, caleosin-like protein, caleosin/peroxygenase, Clo-1, Clo-3, CLO/PXG, CLO3, CYP77B1, epoxygenase, fatty acid epoxygenase, hydrogen peroxide-reducible hemoprotein, hydroperoxide-dependent peroxygenase, peroxygenase RD20, peroxygenase, hydroperoxide-dependent hydroxylase, plant peroxygenase, PXG, PXG1, PXG2, PXG4, RD20, RD20/CLO3, soybean peroxygenase

ECTree

     1 Oxidoreductases
         1.11 Acting on a peroxide as acceptor
             1.11.2 Peroxygenases
                1.11.2.3 plant seed peroxygenase

Systematic Name

Systematic Name on EC 1.11.2.3 - plant seed peroxygenase

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SYSTEMATIC NAME
IUBMB Comments
substrate:hydroperoxide oxidoreductase (RH-hydroxylating or epoxidising)
A heme protein with calcium binding motif (caleosin-type). Enzymes of this type include membrane-bound proteins found in seeds of different plants. They catalyse the direct transfer of one oxygen atom from an organic hydroperoxide, which is reduced into its corresponding alcohol to a substrate which will be oxidized. Reactions catalysed include hydroxylation, epoxidation and sulfoxidation. Preferred substrate and co-substrate are unsaturated fatty acids and fatty acid hydroperoxides, respectively. Plant seed peroxygenase is involved in the synthesis of cutin.