1.11.2.3: plant seed peroxygenase
This is an abbreviated version!
For detailed information about plant seed peroxygenase, go to the full flat file.
Word Map on EC 1.11.2.3
-
1.11.2.3
-
arachidonic
-
epoxyeicosatrienoic
-
epoxide
-
artery
-
cyclooxygenase
-
lipoxygenase
-
vasodilation
-
cyp2j2
-
eicosanoids
-
indomethacin
-
hyperpolarizing
-
miconazole
-
endothelium-derived
-
20-hete
-
dihydroxyeicosatrienoic
-
20-hydroxyeicosatetraenoic
-
ms-ppoh
-
cyp-derived
-
edhfs
-
arteriolar
-
endothelium-dependent
-
oleosins
-
nordihydroguaiaretic
-
vasodilatory
-
dhets
-
preglomerular
-
5,6-epoxyeicosatrienoic
-
large-conductance
-
oxylipins
-
17-octadecynoic
-
eicosatetraynoic
-
cyp-dependent
-
sulfaphenazole
-
hydroxyeicosatetraenoic
-
p450-derived
-
cross-recognition
-
skf525a
-
regioisomeric
-
omega-hydroxylase
-
p450-dependent
-
14,15-epoxyeicosa-5z-enoic
-
11,12-epoxyeicosatrienoic
-
edhf-mediated
-
epoxygenation
-
5,8,11,14-eicosatetraynoic
-
laser-doppler
-
cyp2c11
-
aacocf3
-
iberiotoxin
-
17-odya
- 1.11.2.3
-
arachidonic
-
epoxyeicosatrienoic
- epoxide
- artery
-
cyclooxygenase
- lipoxygenase
-
vasodilation
- cyp2j2
-
eicosanoids
- indomethacin
-
hyperpolarizing
- miconazole
-
endothelium-derived
- 20-hete
-
dihydroxyeicosatrienoic
-
20-hydroxyeicosatetraenoic
-
ms-ppoh
-
cyp-derived
-
edhfs
-
arteriolar
-
endothelium-dependent
-
oleosins
-
nordihydroguaiaretic
-
vasodilatory
-
dhets
-
preglomerular
-
5,6-epoxyeicosatrienoic
-
large-conductance
- oxylipins
-
17-octadecynoic
-
eicosatetraynoic
-
cyp-dependent
- sulfaphenazole
-
hydroxyeicosatetraenoic
-
p450-derived
-
cross-recognition
- skf525a
-
regioisomeric
-
omega-hydroxylase
-
p450-dependent
-
14,15-epoxyeicosa-5z-enoic
-
11,12-epoxyeicosatrienoic
-
edhf-mediated
-
epoxygenation
-
5,8,11,14-eicosatetraynoic
-
laser-doppler
- cyp2c11
- aacocf3
-
iberiotoxin
-
17-odya
Reaction
Synonyms
9-hydroperoxide fatty acid reductase, caleosin, caleosin-like protein, caleosin/peroxygenase, Clo-1, Clo-3, CLO/PXG, CLO3, CYP77B1, epoxygenase, fatty acid epoxygenase, hydrogen peroxide-reducible hemoprotein, hydroperoxide-dependent peroxygenase, peroxygenase RD20, peroxygenase, hydroperoxide-dependent hydroxylase, plant peroxygenase, PXG, PXG1, PXG2, PXG4, RD20, RD20/CLO3, soybean peroxygenase
ECTree
Advanced search results
Natural Substrates Products
Natural Substrates Products on EC 1.11.2.3 - plant seed peroxygenase
Please wait a moment until all data is loaded. This message will disappear when all data is loaded.
REACTION DIAGRAM
(9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + tert-butyl hydroperoxide
(12Z,15Z)-9,10-epoxyoctadeca-12,15-dienoic aicd + (9Z,12Z)-15,16-epoxy-9,12-octadecadienoic acid + ?
-
-
-
-
?
13-hydroperoxyoctadecatrienoic acid + H2O2
13-hydroxyoctadecatrienoic acid + ?
-
-
-
?
13-hydroxyoctadecatrienoic acid + H2O2
15,16-epoxy-13-hydroperoxyoctadecadienoic acid + ?
-
-
-
?
2 linolenic acid + 3 tert-butyl hydroperoxide
(12Z,15Z)-9-epoxyoctadec-12,15-dienoic acid + (12Z)-9,15-diepoxyoctadec-12-enoic acid + 3 tert-butanol
-
-
-
-
?
2-hydroperoxyoctadecatrienoic acid + H2O2
2-hydroxyoctadecatrienoic acid + ?
-
-
-
?
linoleic acid + tert-butyl hydroperoxide
9,10-epoxy-octadecanoic acid + tert-butanol
-
-
-
-
?
linolenic acid + cumene hydroperoxide
linolenic acid 9,10-15,16-diepoxide + ?
74% conversion, physiological linoleic and linolenic acids are the preferred substrates for isoform PXG4
major product, (R),(S)-epoxide enantiomers
-
?
oleic acid + fatty acid hydroperoxide
cis-9,10-epoxystearic acid + ?
-
-
-
-
?
linoleic acid + cumene hydroperoxide
?
-
64% conversion, physiological linoleic and linolenic acids are the preferred substrates for isoform PXG4
-
?
cis-9,10-epoxystearic acid + ?
-
-
-
-
?
?
-
enzyme is an efficient fatty acid epoxygenase, catalyzing the oxidation of cis double bonds of unsaturated fatty acids. The C-12,13 double bond of these unsaturated fatty acids is the least favoured. Isoform PXG4 catalyzes exclusively the formation of (R),(S)-epoxide enantiomers, which is the absolute stereochemistry of the epoxides found in planta. Poor substrate: oleic acid methyl ester
-
-
?
additional information
?
-
-
the enzyme does not oxidize diacylglycerol and triacylglycerol
-
-
?
additional information
?
-
-
peroxygenase exists in nature as a complex with a carotenoid-binding macromolecule
-
-
?