1.11.2.1: unspecific peroxygenase

This is an abbreviated version!
For detailed information about unspecific peroxygenase, go to the full flat file.

Word Map on EC 1.11.2.1

Reaction

RH
+
H2O2
=
ROH
+
H2O

Synonyms

45 kDa peroxygenase/peroxidase, Agrocybe aegerita peroxidase, Agrocybe aegerita peroxidase/peroxygenase, Agrocybe aegerita peroxygenase, APO, aromatic peroxygenase, extracellular peroxygenase, haloperoxidase, haloperoxidase-peroxygenase, heme-thiolate peroxygenase, mushroom peroxygenase, P450st, PII, unspecific heme peroxygenase, UPO, UPO1

ECTree

     1 Oxidoreductases
         1.11 Acting on a peroxide as acceptor
             1.11.2 Peroxygenases
                1.11.2.1 unspecific peroxygenase

Application

Application on EC 1.11.2.1 - unspecific peroxygenase

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APPLICATION
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
analysis
-
use of enzyme for biosensor applications. The substrate spectrum overlaps with those of cytochrome P450s and plant peroxidases which are relevant in environmental analysis and drug monitoring. After immobilization at a chitosan-capped gold-nanoparticle modified glassy carbon electrode, enzyme displays a pair of redox peaks with a midpoint potential of -278.5 mV vs. AgCl/AgCl at 1 M KCl for the Fe2+/Fe3+ redox couple of the heme-thiolate-containing protein. The signal is generated by the reduction of electrode-active reaction products e.g., p-benzoquinone and p-quinoneimine with electroenzymatic recycling of the analyte
additional information
-
Agrocybe aegerita peroxygenase is a particularly potent biocatalyst that fills the gap between cytochrome P450s and common heme peroxidases