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1.11.1.23: (S)-2-hydroxypropylphosphonic acid epoxidase

This is an abbreviated version!
For detailed information about (S)-2-hydroxypropylphosphonic acid epoxidase, go to the full flat file.

Word Map on EC 1.11.1.23

Reaction

(S)-2-hydroxypropylphosphonate
+
H2O2
=
(1R,2S)-1,2-epoxypropylphosphonate
+ 2 H2O

Synonyms

(S)-2-HPP epoxidase, (S)-2-hydroxypropylphosphonate epoxidase, (S)-2-hydroxypropylphosphonic acid epoxidase, (S-HPP) epoxidase, 2-hydroxypropylphosphonic acid epoxidase, EC 1.14.19.7, fom4, fosfomycin-producing epoxidase, HPP epoxidase, HppE, Ps-HppE

ECTree

     1 Oxidoreductases
         1.11 Acting on a peroxide as acceptor
             1.11.1 Peroxidases
                1.11.1.23 (S)-2-hydroxypropylphosphonic acid epoxidase

Natural Substrates Products

Natural Substrates Products on EC 1.11.1.23 - (S)-2-hydroxypropylphosphonic acid epoxidase

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NATURAL SUBSTRATE
NATURAL PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
(R)-2-hydroxypropylphosphonate + H2O2
2-oxo-propylphosphonic acid + H2O
show the reaction diagram
-
-
-
-
?
(R)-2-hydroxypropylphosphonate + H2O2
2-oxopropylphosphonic acid + H2O
show the reaction diagram
-
-
-
?
(R)-2-hydroxypropylphosphonate + NADH + H+ + O2
2-oxopropylphosphonic acid + NAD+ + H2O
show the reaction diagram
-
-
-
-
?
(R)-2-hydroxypropylphosphonic acid + H2O2
2-oxo-propylphosphonic acid + H2O
show the reaction diagram
-
-
-
?
(S)-2-hydroxypropyl-1-phosphonate + H2O2
(1R,2S)-1,2-epoxypropylphosphonate + H2O
show the reaction diagram
-
-
i.e. fosfomycin
-
?
(S)-2-hydroxypropylphosphonate + H2O2
(1R,2S)-1,2-epoxypropylphosphonate + H2O
show the reaction diagram
(S)-2-hydroxypropylphosphonate + H2O2
cis-fosfomycin + trans-fosfomycin + 2 H2O
show the reaction diagram
-
-
-
?
(S)-2-hydroxypropylphosphonate + NADH + H+ + O2
(1R,2S)-epoxypropylphosphonate + NAD+ + H2O
show the reaction diagram
-
-
i.e. fosfomycin
-
?
(S)-2-hydroxypropylphosphonic acid + 2 NADH + O2
cis-(1R,2S)-epoxypropylphosphonic acid + 2 H2O + 2 NAD+
show the reaction diagram