1.11.1.18: bromide peroxidase

This is an abbreviated version!
For detailed information about bromide peroxidase, go to the full flat file.

Word Map on EC 1.11.1.18

Reaction

RH
+
HBr
+
H2O2
=
RBr
+ 2 H2O

Synonyms

apobromoperoxidase I, BPO, BPO 1, BPO 2, BPO I, BPO-A1, BPO-A2, BPO1, bromoperoxidase, bromoperoxidase A2, bromoperoxidase I, bromoperoxidase-catalase, BrPO, CoVBPO, CVBPO, EC 1.11.1.10, HAP phytase, More, non-haem bromoperoxidase, non-haem bromoperoxidase BPO 1, non-haem bromoperoxidase BPO 2, non-haem bromoperoxidase BPO-A2, non-heme haloperoxidases, non-heme-type bromoperoxidase, nonhaem-type bromoperoxidase BPO 1a, nonhaem-type bromoperoxidase BPO 1b, nonhaem-type bromoperoxidase BPO 3, nonheme bromoperoxidase, nVBPO, rVBPO, St-Phy, sVBPO, V-BPO, V-BrPO, vanadate haloperoxidase, vanadate-dependent bromoperoxidase I, vanadium bromoperoxidase, vanadium containing bromoperoxidase, vanadium-containing bromoperoxidase, vanadium-dependent bromoperoxidase, vanadium-dependent bromoperoxidase 2, vanadium-dependent haloperoxidase, vanadium-dependent peroxidase, vBPO, VBPO1, VBPO2, VBrPO(AnI)

ECTree

     1 Oxidoreductases
         1.11 Acting on a peroxide as acceptor
             1.11.1 Peroxidases
                1.11.1.18 bromide peroxidase

Substrates Products

Substrates Products on EC 1.11.1.18 - bromide peroxidase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
Br- + H2O2 + (3E,6R,7R)-laurediol
deacetyllaurencin + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + (3R)-3-bromo-2,6-dimethylhept-5-en-2-ol
3,5-dibromo-2,6-dimethylheptane-2,6-diol + H2O
show the reaction diagram
-
-
70% yield, at pH 6.0
-
?
Br- + H2O2 + 1,1-dimethyl-4-chloro-3,5-cyclohexanedione
?
show the reaction diagram
Br- + H2O2 + 1,1-dimethyl-4-chloro-3,5-cyclohexanedione
bromochlorodimedone + ?
show the reaction diagram
-
i.e. monochlorodimedone
-
-
?
Br- + H2O2 + 1-methoxynaphthalene
1-methoxy-4-bromonaphthalene + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + 1-phenylpent-4-en-1-ol
4-bromo-1-phenylpentane-1,5-diol + 5-bromo-1-phenylpentane-1,4-diol + 2-(bromomethyl)-5-phenyltetrahydrofuran + H2O
show the reaction diagram
-
-
30% yield of 4-bromo-1-phenylpentane-1,5-diol, 28% yield of 5-bromo-1-phenylpentane-1,4-diol, and 25% yield of 2-(bromomethyl)-5-phenyltetrahydrofuran, at pH 6.0
-
?
Br- + H2O2 + 2,4,6-tribromophenol
1,3,6,8-tetrabromodibenzo-p-dioxin
show the reaction diagram
-
-
formation of ppb-level yields of 1,3,6,8-tetrabromodibenzo-p-dioxin through direct condensation. Additionally, 1,3,7,9-tetrabromodibenzo-p-dioxin, 1,2,4,7-tetrabromodibenzo-p-dioxin, and/or 1,2,4,8-tetrabromodibenzo-p-dioxin and 1,3,7-tribromodibenzo-p-dioxin and 1,3,8-tribromodibenzo-p-dioxin are frequently formed but at lower yields. Reaction probably proceeds via bromine shifts or Smiles rearrangements, whereas the tribromodibenzo-p-dioxins may result from subsequent debromination processes
-
?
Br- + H2O2 + 2-hydroxybenzyl alcohol
2,4,6-tribromobenzyl alcohol + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + 2-methoxyphenol
2-bromo-6-methoxyphenol + 4-bromo-6-methoxyphenol + H2O
show the reaction diagram
-
56% of product, in a 21/79 mixture of o-/p-regioisomers, plus 10% 2,4-dibromo-6-methoxyphenol
-
?
Br- + H2O2 + 2-methylphenol
2-bromo-6-methylphenol + 4-bromo-6-methylphenol + H2O
show the reaction diagram
-
68% of product, in a 16/84 mixture of o-/p-regioisomers, plus 4% 2,4-dibromophenol
-
?
Br- + H2O2 + 2-t-butylphenol
2-bromo-6-t-butylphenol + 4-bromo-6-t-butylphenol + H2O
show the reaction diagram
-
42% of product, in a 36/64 mixture of o-/p-regioisomers, plus 2% 2,4-dibromo-6-t-butylphenol
-
?
Br- + H2O2 + 4-pentynoic acid
(5E)-bromomethylidenetetrahydro-2-furanone
show the reaction diagram
-
catalyzes the bromolactonization of 4-pentynoic acid forming (5E)-bromomethylidenetetrahydro-2-furanone. Formation of the bromofuranone likely results from an initial bromination reaction at the terminal alkyne, followed by cyclization from intermolecular nucleophilic attack by the terminal hydroxyl group
-
-
?
Br- + H2O2 + 5-methyl-1-phenylhex-4-en-1-ol
4-bromo-5-methyl-1-phenylhexane-1,5-diol + 2-(1-bromo-1-methylethyl)-5-phenyltetrahydrofuran + 3-bromo-2,2-dimethyl-6-phenyltetrahydro-2H-pyran + H2O
show the reaction diagram
-
-
69% yield of 4-bromo-5-methyl-1-phenylhexane-1,5-diol, 6% yield of 2-(1-bromo-1-methylethyl)-5-phenyltetrahydrofuran, and 9% yield of 3-bromo-2,2-dimethyl-6-phenyltetrahydro-2H-pyran, at pH 6.0
-
?
Br- + H2O2 + aniline
o-bromoaniline + p-bromoaniline + ?
show the reaction diagram
Br- + H2O2 + anisole
p-bromoanisole + o-bromoanisole + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + cyclohexene
trans-1-hydroxy-2-bromocyclohexane
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + cytidine
5-bromocytidine + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + cytosine
5-bromocytosine + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + methyl pyrrole-2-carboxylate
methyl 4-bromo-1H-pyrrole-2-carboxylate + methyl 5-bromo-1H-pyrrole-2-carboxylate + H2O
show the reaction diagram
-
-
quantitative conversion within 24 h, 94% of product in 93/7 ratio of 4-/5-substituted regioisomers
-
?
Br- + H2O2 + methyl pyrrole-2-carboxylate
methyl 5-amino-4-bromocyclopenta-1,3-diene-1-carboxylate + methyl 5-amino-3-bromocyclopenta-1,3-diene-1-carboxylate + methyl 5-amino-3,4-dibromocyclopenta-1,3-diene-1-carboxylate + H2O
show the reaction diagram
-
-
5% yield of methyl 5-amino-4-bromocyclopenta-1,3-diene-1-carboxylate, 59% yield of methyl 5-amino-3-bromocyclopenta-1,3-diene-1-carboxylate, and 5% yield of methyl 5-amino-3,4-dibromocyclopenta-1,3-diene-1-carboxylate, at pH 6.3 and 25°C
-
?
Br- + H2O2 + monochlorodimedon
?
show the reaction diagram
-
-
-
?
Br- + H2O2 + monochlorodimedone
?
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + monochlorodimedone
? + H2O
show the reaction diagram
Br- + H2O2 + monochlorodimedone
H2O + ?
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + monochlorodimedone
monobromo-monochlorodimedone + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + o-dianisidine
?
show the reaction diagram
Br- + H2O2 + phenol
2,4,6-tribromophenol + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + phenol
2-bromophenol + 4-bromophenol + H2O
show the reaction diagram
-
69% of product, in a 91/9 mixture of o-/p-regioisomers, plus 3% 2,4-dibromo-6-methylphenol and some 2,4,6-tribromophenol
-
?
Br- + H2O2 + phenol red
phenol blue + ?
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + pyrazole
4-bromopyrazole + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + styrene
DL-1 -bromo-2-hydroxy-2-phenylethane + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + thiophene
2-bromothiophene + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + trans-cinnamic acid
(+/-)-erythro-2-bromo-3-hydroxy-3-phenylpropionic acid + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + trans-cinnamyl alcohol
(+/-)-1,3-dihydroxy-2-bromo-3-phenylpropane + H2O
show the reaction diagram
-
-
-
-
?
Br- + H2O2 + uracil
5-bromouracil + H2O
show the reaction diagram
-
-
-
-
?
Capso + Br- + peracetic acid
?
show the reaction diagram
cytosine + Br- + peracetic acid
5-bromocytosine + ?
show the reaction diagram
Hepes + Br- + peracetic acid
?
show the reaction diagram
I- + H2O2
triiodide + ?
show the reaction diagram
I- + H2O2 + monochlorodimedone
? + H2O
show the reaction diagram
-
-
-
?
I- + H2O2 + o-dianisidine
?
show the reaction diagram
I- + H2O2 + pyrazole
4-iodopyrazole + H2O
show the reaction diagram
-
-
-
-
?
I- + H2O2 + uracil
5-iodouracil + H2O
show the reaction diagram
-
-
-
-
?
KBr + 2 H2O
KH + HBr + H2O2
show the reaction diagram
-
-
-
?
monochlorodimedone + Br- + H2O2
?
show the reaction diagram
Mops + Br- + peracetic acid
5-bromocytosine + ?
show the reaction diagram
phenol + H2O2 + Br-
4-bromophenol + 2-bromophenol + H2O
show the reaction diagram
-
-
4-bromophenol + 2-bromophenol at the ratio of 4:1
-
?
taurine + Br- + peracetic acid
bromotaurine + ?
show the reaction diagram
Tes + Br- + peracetic acid
?
show the reaction diagram
Tris + Br- + peracetic acid
?
show the reaction diagram
additional information
?
-