1.11.1.10: chloride peroxidase

This is an abbreviated version!
For detailed information about chloride peroxidase, go to the full flat file.

Word Map on EC 1.11.1.10

Reaction

RH
+
chloride
+
H2O2
=
RCl
+ 2 H2O

Synonyms

CCPO, Chloride peroxidase, chloroperoxidase, choroperoxidase, CPO, CPO-I, CPO2, heme-thiolate chloroperoxidase, peroxidase, chloride, Vanadium chloride peroxidase, vCPO

ECTree

     1 Oxidoreductases
         1.11 Acting on a peroxide as acceptor
             1.11.1 Peroxidases
                1.11.1.10 chloride peroxidase

Substrates Products

Substrates Products on EC 1.11.1.10 - chloride peroxidase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(+/-)-citronellol + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
(+/-)-linalool + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
(-)-alpha-pinene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
(-)-beta-pinene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
(1R,2S)-(+)-2-benzylcyclopropylmethanol + tert-butyl hydroperoxide
(1S,2R)-(+)-2-benzyl-1-formylcyclopropane + ?
show the reaction diagram
-
-
-
0
?
(1R,2S)-(+)-2-ethylcyclopropylmethanol + tert-butyl hydroperoxide
(1S,2R)-(-)-2-ethyl-1-formylcyclopropane + ?
show the reaction diagram
-
-
-
0
?
(1R,2S)-(+)-2-methylcyclopropanemethanol + tert-butyl hydroperoxide
(1S,2R)-(-)-2-methyl-1-formylcyclopropane + ?
show the reaction diagram
-
-
-
0
?
(1R,2S)-(+)-2-propylcyclopropylmethanol + tert-butyl hydroperoxide
(1S,2R)-(-)-1-formyl-2-propylcyclopropane + ?
show the reaction diagram
-
-
-
0
?
(1R,2S)-(-)-2-acetoxymethylcyclopropylmethanol + tert-butyl hydroperoxide
(1S,2R)-2-acetoxymethyl-1-formylcyclopropane + ?
show the reaction diagram
-
-
-
0
?
(1R,2S)-cyclohexa-3,5-diene-1,2-diyl diacetate + tert-butyl hydroperoxide
(1S,2S,3S,6S)-7-oxabicyclo[4.1.0]hept-4-ene-2,3-diyl diacetate + (1R,2S,5R,6S)-5,6-dihydroxycyclohex-3-ene-1,2-diyl diacetate + ?
show the reaction diagram
-
-
-
0
?
(1S)-3-carene + Cl- + H2O2
(1S,3R,4R,6R)-4-chloro-3,7,7-trimethyl-bicyclo[4.1.0]heptane-3-ol + H2O
show the reaction diagram
-
-
-
0
?
(2E)-hex-2-en-1-ol + tert-butyl hydroperoxide
trans-(3-propyloxiran-2-yl)methanol + H2O
show the reaction diagram
-
-
-
0
?
(2Z)-hex-2-en-1-ol + tert-butyl hydroperoxide
cis-(3-propyloxiran-2-yl)methanol + H2O
show the reaction diagram
-
-
-
0
?
(2Z)-pent-2-en-1-ol + tert-butyl hydroperoxide
cis-2-(3-ethyloxiran-2-yl)ethanol + (3Z)-hex-3-enal + H2O
show the reaction diagram
-
-
-
0
?
(3E,5E)-hepta-3,5-dien-2-one + tert-butyl hydroperoxide
(2E,4E)-6-oxohepta-2,4-dienal + (3E)-4-(3-methyloxiran-2-yl)but-3-en-2-one + (2E)-4-oxopent-2-enal
show the reaction diagram
-
-
83% (2E,4E)-6-oxohepta-2,4-dienal, 4% (3E)-4-(3-methyloxiran-2-yl)but-3-en-2-one, and 13% (2E)-4-oxopent-2-enal
0
?
(3Z,5E)-hepta-3,5-dien-2-one + tert-butyl hydroperoxide
(2E,4Z)-6-oxohepta-2,4-dienal + (2E)-4-oxopent-2-enal + (2E,4E)-6-oxohepta-2,4-dienal
show the reaction diagram
-
-
78% (2E,4Z)-6-oxohepta-2,4-dienal, 15% (2E)-4-oxopent-2-enal and 7% (2E,4E)-6-oxohepta-2,4-dienal
0
?
(3Z,5Z)-hepta-3,5-dien-2-one + tert-butyl hydroperoxide
(2E,4Z)-6-oxohepta-2,4-dienal + (2E)-4-oxopent-2-enal + (3Z)-4-[(2S,3S)-3-methyloxiran-2-yl]but-3-en-2-one
show the reaction diagram
-
-
27% (2E,4Z)-6-oxohepta-2,4-dienal, 38% (3E)-4-(3-methyloxiran-2-yl)but-3-en-2-one and 35% (3Z)-4-[(2S,3S)-3-methyloxiran-2-yl]but-3-en-2-one
0
?
(4Z)-hex-4-en-1-ol + tert-butyl hydroperoxide
3-(3-methyloxiran-2-yl)propan-1-ol + (4Z)-hex-4-enal + H2O
show the reaction diagram
-
-
-
0
?
(5R,6S)-5,6-dimethoxycyclohexa-1,3-diene + tert-butyl hydroperoxide
(1S,4S,5S,6S)-4,5-dimethoxy-7-oxabicyclo[4.1.0]hept-2-ene + ?
show the reaction diagram
-
-
-
0
?
(R)-limonene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
(R)-limonene + H2O2
(1S,2S,4R)-limonene-1,2-diol + (1R,2R)-4R-limonene-1,2-diol + ?
show the reaction diagram
-
when the reaction is carried out in the presence of chloride ions an enhancement in the reaction rate is observed, maintaining the regioselectivity, but not the stereoselectivity. The reaction products under these conditions are (1S,2S)-4R-limonene-1,2-diol and (1R,2R)-4R-limonene-1,2-diol. In the presence of potassium chloride the limonene oxidation also occurs by the produced hypochlorite without stereoselectivity
-
0
?
(R)-limonene + H2O2
(1S,2S,4R)-limonene-1,2-diol + H2O
show the reaction diagram
-
in the absence of chloride ions, at pH 3 or pH 6, the reaction is regio and stereoselective with a diasteromeric excess of more than 99% of (1S,2S)-4R-limonene-1,2-diol
-
0
?
(Z)-beta-ocimene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
1,2-dihydronaphthalene + tert-butyl hydroperoxide
(1R,2R)-dihydroxytetrahydronaphthalene + ?
show the reaction diagram
-
-
-
0
?
1,3-cycloheptadiene + tert-butyl hydroperoxide
(1R,3R)-cyclohept-3-ene-1,2-diol + (1R,4S)cyclohept-2-ene-1,4-diol + (1R,4R)-cyclohept-2-ene-1,4-diol + ?
show the reaction diagram
-
-
-
0
?
1,3-cyclooctadiene + tert-butyl hydroperoxide
cycloocta-1,4-dien-1-yl hydroperoxide + cycloocta-2,4-dien-1-ol + ?
show the reaction diagram
-
-
main product is cycloocta-1,4-dien-1-yl hydroperoxide, formation of small amounts of cycloocta-2,4-dien-1-ol
0
?
2 pyrene + 3 KCl + 3 H2O2
chloropyrene + dichloropyrene + 3 KOH + 3 H2O
show the reaction diagram
-
-
-
0
?
2'-deoxyuridine + Br- + H2O2
5-bromo-2'-deoxyuridine + H2O
show the reaction diagram
-
-
-
?
2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) + H2O2 + HCl
?
show the reaction diagram
-
-
-
0
?
2,3,5,6-tetrachloroaniline + HCl + H2O2
pentachloroaniline + H2O
show the reaction diagram
-
the main product from peroxidase oxidation is a polymeric and insoluble material
-
0
?
2,3,5,6-tetrachlorophenol + Cl- + H2O2
pentachlorophenol + H2O
show the reaction diagram
-
-
-
0
?
2,3,5,6-tetrachlorophenol + HCl + H2O2
pentachlorophenol + H2O
show the reaction diagram
-
the main product from peroxidase oxidation is a polymeric and insoluble material
-
0
?
2,4,6-trichlorophenol + H2O2
2,6-dichloro-1,4-benzoquinone + H2O + HCl
show the reaction diagram
-
-
-
0
?
2,4,6-trichlorophenol + H2O2
?
show the reaction diagram
-
oxidative dehylogenation
-
0
?
2,4-dichlorophenol + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
2-aminophenol + H2O2
?
show the reaction diagram
-
-
-
0
?
2-methyl-4-propylcyclopentane-1,3-dione + Cl- + H2O2
2-chloro-2-methyl-4-propylcyclopentane-1,3-dione + H2O
show the reaction diagram
-
reaction without appreciable stereoselectivity
-
?
2-methylanthracene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
3,4-dichloroaniline + H2O2
?
show the reaction diagram
-
-
-
0
?
3-amino-1-propanol + H2O2
3-aminopropanal + H2O
show the reaction diagram
-
44% conversion
-
0
?
3-amino-1-propanol + tert-butyl hydroperoxide
3-aminopropanal + H2O + ?
show the reaction diagram
-
83.6% conversion
-
0
?
3-aminophenol + H2O2
?
show the reaction diagram
-
-
-
0
?
3-anisidine + H2O2
?
show the reaction diagram
-
-
-
0
?
4,6-dimethyldibenzothiophene + Cl- + H2O2
?
show the reaction diagram
-
the substrate exists as a monomeric and dimeric species in aqueous acetonitrile solutions. Oxidation of dimer substrate is preferred when compared to monomer oxidation
-
0
?
4-aminobenzoic acid + H2O2
?
show the reaction diagram
-
-
-
0
?
4-aminophenol + H2O2
?
show the reaction diagram
-
-
-
0
?
4-anisidine + H2O2
?
show the reaction diagram
-
-
-
0
?
4-chloroaniline + chloride + H2O2
?
show the reaction diagram
-
-
-
0
?
4-chloroaniline + H2O2
4-chloronitrosobenzene + H2O
show the reaction diagram
-
-
-
0
?
4-chlorophenol + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
4-chlorophenol + H2O2
?
show the reaction diagram
-
-
-
0
?
4-chlorophenol + H2O2 + Cl-
?
show the reaction diagram
-
-
-
0
?
4-fluorophenol + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
4-fluorophenol + H2O2
1,4-benzoquinone + ?
show the reaction diagram
-
-
-
0
?
4-toluidine + H2O2
?
show the reaction diagram
-
-
-
0
?
5-hexen-1-ol + tert-butyl hydroperoxide
5-hexenal + ?
show the reaction diagram
-
-
only a small amount is produced
0
?
5-hexen-1-ol + tert-butyl hydroperoxide
hex-5-enal + H2O
show the reaction diagram
-
-
-
0
?
7,12-dimethylbenzanthracene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
7-azaindole + H2O2
7-azaoxindole + H2O
show the reaction diagram
-
cross-linked enzyme aggregates
-
0
?
7-methylbenzo[a]pyrene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
9-methylanthracene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
acenaphthene + Cl- + H2O2
dichloroacenaphthene + trichloroacenaphthene + H2O
show the reaction diagram
-
-
-
?
alizarin red S + Cl- + H+ + H2O2
? + 2 H2O
show the reaction diagram
98.2% efficiency, degradation to nine different products
-
0
?
anthracene + 2 KCl + 2 H2O2
9,10-dichloroanthracene + 2 KOH + 2 H2O
show the reaction diagram
-
-
-
0
?
anthracene + Cl- + H2O2
9,10-dichloroanthracene + H2O
show the reaction diagram
-
-
-
?
azulene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
azure B + Cl- + H+ + H2O2
? + 2 H2O
show the reaction diagram
benzo[a]pyrene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
benzo[ghi]perylene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
benzyl N-(2-hydroxyethyl)carbamate + H2O2
? + H2O
show the reaction diagram
benzyl N-(2-hydroxyethyl)carbamate + tert-butyl hydroperoxide
? + H2O
show the reaction diagram
benzyl-N-(2-hydroxyethyl)-carbamate + tertbutyl hydroperoxide
Cbz-glycinal + ?
show the reaction diagram
-
-
-
0
?
benzyloxycarbonyl ethanolamine + tert-butyl hydroperoxide
benzyloxycarbonyl glycinal
show the reaction diagram
-
-
-
0
?
beta-myrcene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
biphenylene + Cl- + H2O2
dichlorobiphenylene + trichlorobiphenylene + H2O
show the reaction diagram
-
-
-
?
Boc-D-methionine-methyl ester + H2O2
Boc-D-methionine-methyl ester sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
Boc-L-methionine-methyl ester + H2O2
Boc-L-methionine-methyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
Br- + H2O2 + 1,1-dimethyl-4-chloro-3,5-cyclohexanedione
?
show the reaction diagram
-
i.e. monochlorodimedone
-
0
?
carvacrol + Cl- + H2O2
chlorocarvacrol + H2O
show the reaction diagram
-
-
0
?
cis-2-hexen-1-ol + tert-butyl hydroperoxide
cis-2-hexenal + ?
show the reaction diagram
-
-
further production of small amounts of trans-2-hexenal, cis-3-hexenal and trans-3-hexenal
0
?
cis-2-phenylcyclopropylmethanol + tert-butyl hydroperoxide
?
show the reaction diagram
-
-
-
0
?
cis-3-hexen-1-ol + tert-butyl hydroperoxide
cis-3-hexenal + ?
show the reaction diagram
-
-
further production of small amounts of cis-2-hexenal, trans-2-hexenal and trans-3-hexenal
0
?
cis-4-hexen-1-ol + tert-butyl hydroperoxide
cis-4-hexenal + cis-4,5-epoxyhexan-1-ol + ?
show the reaction diagram
-
-
further production of small amounts of trans-4,5-epoxyhexan-1-ol and trans-4-hexenal
0
?
cis-beta-methylstyrene + chloride + H2O2
?
show the reaction diagram
-
-
the enzyme produced (1S2R)- and (1R2S)-epoxides at a 96:4 product ratio
0
?
cis-cyclohexa-3,5-diene-1,2-diol + tert-butyl hydroperoxide
(1R,2S,3S,4S)-cyclohex-5-ene-1,2,3,4-tetrol + ?
show the reaction diagram
-
-
+ traces of (1R,2S,3S,6S)-7-oxabicyclo[4.1.0]hept-4-ene-2,3-diol
0
?
Cl2O2 + H+
Cl- + ClO2 + H2O
show the reaction diagram
-
dismutation
-
?
ClO2 + H2O
Cl- + ClO3- + O2 + H+
show the reaction diagram
-
dismutation
-
?
crystal violet + Cl- + H+ + H2O2
? + 2 H2O
show the reaction diagram
97.7% efficiency, degradation to three products
-
0
?
cytidine + Br- + H2O2
5-bromocytidine + H2O
show the reaction diagram
-
-
-
?
cytosine + Br- + H2O2
?
show the reaction diagram
-
-
-
0
?
fluoranthene + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
fluorene + Cl- + H2O2
dichlorofluorene + H2O
show the reaction diagram
-
-
-
?
gentian violet + Cl- + H+ + H2O2
? + 2 H2O
show the reaction diagram
geraniol + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
guaiacol + H2O2
tetraguaiacol + H2O
show the reaction diagram
-
-
-
0
?
guanosine + Br- + H2O2
8-bromoguanosine + H2O
show the reaction diagram
-
-
-
?
H2O2
H2O + O2
show the reaction diagram
-
-
-
?
H2O2 + methylene blue
oxidized methylene blue + H2O
show the reaction diagram
-
-
-
0
?
indole + chloride + H2O2
?
show the reaction diagram
-
-
-
0
?
indole + Cl- + H2O2
oxindole + monochloroindole + H2O
show the reaction diagram
-
-
-
0
?
indole + H2O2
2-oxindole + H2O
show the reaction diagram
indole + H2O2
2-oxoindole + H2O
show the reaction diagram
indole + tert-butyl hydroperoxide
2-oxoindole + ?
show the reaction diagram
-
-
-
0
?
isoplagiochin C + Cl- + H2O2
?
show the reaction diagram
Met + Cl- + H2O2
?
show the reaction diagram
-
-
-
0
?
methyl orange + Cl- + H+ + H2O2
? + 2 H2O
show the reaction diagram
monochlordimedone + KCl + H2O2 + tert-butyl hydroperoxide
?
show the reaction diagram
-
-
-
0
?
monochlorodimedon + Cl- + H2O2
dichlorodimedon + H2O
show the reaction diagram
monochlorodimedone + Br- + H2O2
monobromo-monochlorodimedone + H2O
show the reaction diagram
monochlorodimedone + chloride + H2O2
dichlorodimedone + H2O
show the reaction diagram
monochlorodimedone + Cl- + H2O2
dichlorodimedone + H2O
show the reaction diagram
monochlorodimedone + H2O2 + HCl
dichloromedone + H2O
show the reaction diagram
-
-
-
0
?
monochlorodimedone + HCl + H2O2
?
show the reaction diagram
-
-
-
0
?
monochlorodimedone + KCl + H2O2
?
show the reaction diagram
-
cross-linked enzyme aggregates
-
0
?
monochlorodimedone + KCl + H2O2
dichlorodimedone + KOH + H2O
show the reaction diagram
-
-
-
0
?
N,N,N',N'-tetramethylphenylene diamine + H2O2 + HCl
?
show the reaction diagram
-
-
-
0
?
N-acetyl-L-methionine-methyl ester + H2O2
N-acetyl-L-methionine-methyl ester (RS)-sulfoxide
show the reaction diagram
-
-
-
0
?
N-Cbz-3-amino-1-propanol + H2O2
N-Cbz-3-aminopropanal + H2O
show the reaction diagram
-
9.7% conversion
-
0
?
N-Cbz-3-amino-1-propanol + tert-butyl hydroperoxide
N-Cbz-3-aminopropanal + H2O + ?
show the reaction diagram
-
10.9% conversion
-
0
?
N-Cbz-5-aminopentanol + H2O2
N-Cbz-5-aminopentanal + H2O
show the reaction diagram
-
16.3% conversion
-
0
?
N-Cbz-5-aminopentanol + tert-butyl hydroperoxide
N-Cbz-5-aminopentanal + H2O + ?
show the reaction diagram
-
16.8% conversion
-
0
?
N-Cbz-6-aminohexanol + H2O2
N-Cbz-6-aminohexanal + H2O
show the reaction diagram
-
12.3% conversion
-
0
?
N-Cbz-6-aminohexanol + tert-butyl hydroperoxide
N-Cbz-6-aminohexanal + H2O + ?
show the reaction diagram
-
9.4% conversion
-
0
?
N-chloroacetyl-L-methionine-methyl ester + H2O2
N-chloroacetyl-L-methionine-methyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-formyl-L-methionine-methyl ester + H2O2
N-formyl-L-methionine-methyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-methoxycarbonyl-D-ethionine-methyl ester + H2O2
N-methoxycarbonyl-D-ethionine-methyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-methoxycarbonyl-D-methionine-ethyl ester + H2O2
N-methoxycarbonyl-D-methionine-ethyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-methoxycarbonyl-D-methionine-methyl ester + H2O2
N-methoxycarbonyl-D-methionine-methyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-methoxycarbonyl-D-methionine-n-butyl ester + H2O2
N-methoxycarbonyl-D-methionine-n-butyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-methoxycarbonyl-D-methionine-n-propyl ester + H2O2
N-methoxycarbonyl-D-methionine-n-propyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-methoxycarbonyl-L-ethionine-ethyl ester + H2O2
N-methoxycarbonyl-L-ethionine-ethyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-methoxycarbonyl-L-ethionine-methyl ester + H2O2
N-methoxycarbonyl-L-ethionine-methyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-methoxycarbonyl-L-methionine-ethyl ester + H2O2
N-methoxycarbonyl-L-methionine-ethyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-methoxycarbonyl-L-methionine-methyl ester + H2O2
N-methoxycarbonyl-L-methionine-methyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-methoxycarbonyl-L-methionine-n-butyl ester + H2O2
N-methoxycarbonyl-L-methionine-n-butyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-methoxycarbonyl-L-methionine-n-pentyl ester + H2O2
N-methoxycarbonyl-L-methionine-n-pentyl ester (RS)-sulfoxide + H2O
show the reaction diagram
-
-
-
0
?
N-methoxycarbonyl-L-methionine-n-propyl ester + H2O2
N-methoxycarbonyl-L-methionine-n-propyl ester (RS)-sulfoxide + H2O
show the reaction diagram
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0
?
naphthalene + Cl- + H2O2
?
show the reaction diagram
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0
?
naphthalene + KCl + H2O2
chloronaphthalene + KOH + H2O
show the reaction diagram
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0
?
nerol + Cl- + H2O2
?
show the reaction diagram
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0
?
nuclear fast red + Cl- + H+ + H2O2
? + 2 H2O
show the reaction diagram
orange G + Br- + H+ + H2O2
? + 2 H2O
show the reaction diagram
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0
?
p-nitrostyrene + H2O2
p-nitrostyrene oxide + H2O
show the reaction diagram
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0
?
pentachlorophenol + Cl- + H2O2
?
show the reaction diagram
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0
?
pentachlorophenol + HCl + H2O
?
show the reaction diagram
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the main product from peroxidase oxidation is a polymeric and insoluble material
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0
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perylene + Cl- + H2O2
?
show the reaction diagram
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0
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phenanthrene + Cl- + H2O2
chlorophenanthrene + H2O
show the reaction diagram
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?
pyrazole + Br- + H2O2
4-bromopyrazole + H2O
show the reaction diagram
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pyrazole + Cl- + H2O2
4-chloropyrazole + H2O
show the reaction diagram
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pyrazole + I- + H2O2
4-iodopyrazole + H2O
show the reaction diagram
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pyrene + Cl- + H2O2
chloropyrene + dichloropyrene + H2O
show the reaction diagram
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pyrogallol + chloride + H2O2
?
show the reaction diagram
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0
?
pyrogallol + H2O2
?
show the reaction diagram
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0
?
RH + chloride + H2O2
RCl + H2O
show the reaction diagram
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0
?
styrene + H2O2
?
show the reaction diagram
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native enzyme is conjugated with polystyrene to form a surfactant-like structure that self assembled at oil-water interfaces. The interface-assembly of the enzyme improves the overall catalytic efficiency as compared to traditional biphasic reactions with enzymes contained in bulk aqueous phase. The interfacial placement of the enzyme can suppress unwanted side reactions including the hydrolysis of the styrene epoxide product
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0
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styrene + tert-butyl hydroperoxide
styrene oxide + ?
show the reaction diagram
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0
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sulfur mustard + chloride + H2O2
sulfur mustard sulfoxide + H2O
show the reaction diagram
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0
?
thianthrene + H2O2 + Cl-
?
show the reaction diagram
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0
?
thioanisole + H2O2
(R)-methyl phenyl sulfoxide + H2O
show the reaction diagram
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0
?
thioanisole + H2O2
?
show the reaction diagram
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0
?
thioanisole + H2O2
methyl phenyl sulfoxide + H2O
show the reaction diagram
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0
?
thioanisole + H2O2
methyl-phenyl sulfoxide + ?
show the reaction diagram
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?
thioanisole + H2O2 + Cl-
?
show the reaction diagram
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0
?
thioanisole + HCl + H2O2
?
show the reaction diagram
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formation and decay of hydroperoxo-ferric intermediate in CPO via an oxygenase/oxidase pathway is documented
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0
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thiourea + Cl- + H2O2
?
show the reaction diagram
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0
?
thymine + Br- + H2O2
5-bromo-6-hydroxy-5,6-dihydrothymine + H2O
show the reaction diagram
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?
thymol + Br- + H2O2
bromothymol + H2O
show the reaction diagram
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0
?
thymol + Cl- + H2O2
p-chlorothymol + o-chlorothymol + H2O
show the reaction diagram
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0
?
trans-2-hexen-1-ol + tert-butyl hydroperoxide
trans-2-hexenal + ?
show the reaction diagram
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further production of small amounts of cis-2-hexenal,cis-3-hexenal and trans-3-hexenal
0
?
trans-2-phenylcyclopropylmethanol + tert-butyl hydroperoxide
?
show the reaction diagram
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formation of the aldehyde with poor enantioselectivity
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0
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trans-3,4-dimethoxycinnamic acid + Br- + H2O2 + H+
DL-1,1-dibromo-2-hydroxy-2-(3,4-dimethoxy-5-bromophenyl)ethane + DL-1,1-dibromo-2-hydroxy-2-(3,4-dimethoxyphenyl)ethane + 2-bromo-3-hydroxy-3-(3,4-dimethoxyphenyl)propionic acid + H2O
show the reaction diagram
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trans-3,4-dimethoxycinnamic acid + Cl- + H2O2 + H+
trans-1-chloro-2-(3,4-dimethoxy-5-chlorophenyl)ethylene + trans-1-chloro-2-(3,4-dimethoxyphenyl)ethylene + DL-1,1-dichloro-2-hydroxy-2-(3,4-dimethoxyphenyl)ethane
show the reaction diagram
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?
trans-3-hexen-1-ol + tert-butyl hydroperoxide
trans-3-hexenal + ?
show the reaction diagram
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further production of small amounts of cis-3-hexenal, trans-2-hexenal and cis-3-hexenal
0
?
trans-4-hexen-1-ol + tert-butyl hydroperoxide
trans-2-(3-ethyloxiran-2-yl)ethanol + (3E)-hex-3-enal + H2O
show the reaction diagram
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0
?
trans-4-hexen-1-ol + tert-butyl hydroperoxide
trans-4,5-epoxyhexan-1-ol + trans-4-hexenal + H2O + ?
show the reaction diagram
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0
?
trans-4-hexen-1-ol + tert-butyl hydroperoxide
trans-4-hexenal + trans-4,5-epoxyhexan-1-ol + ?
show the reaction diagram
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further production of small amounts of cis-4,5-epoxyhexan-1-ol and cis-4-hexenal
0
?
trans-4-hydroxycinnamic acid + Br- + H+ + H2O2
trans-1-bromo-2-(4-hydroxyphenyl)ethylene + H2O
show the reaction diagram
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?
trans-4-hydroxycinnamic acid + Cl- + H+ + H2O2
trans-1-chloro-2-(4-hydroxyphenyl)ethylene + H2O
show the reaction diagram
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?
trans-4-methoxy-cinnamic acid + Br- + H+ + H2O2
2,3-dihydroxy-3-(4-methoxyphenyl)propionic acid + DL-1,1-dibromo-2-hydroxy-2-(4-methoxyphenyl)ethane + H2O
show the reaction diagram
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trans-cinnamic acid + H2O2 + Br- + H+
trans-1-bromo-2-phenylethylene + erythro-2-bromo-3-hydroxy-3-phenylpropionic acid + H2O
show the reaction diagram
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triphenylene + Cl- + H2O2
chlorotriphenylene + H2O
show the reaction diagram
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?
tyrosine + Br- + H2O2
?
show the reaction diagram
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0
?
tyrosine + Br- + H2O2
monobromotyrosine + dibromotyrosine
show the reaction diagram
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?
tyrosine + Cl- + H2O2
monochlorotyrosine + dichlorotyrosine
show the reaction diagram
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tyrosine + I- + H2O2
?
show the reaction diagram
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0
?
uracil + Br- + H2O2
5-bromouracil + H2O
show the reaction diagram
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uracil + Cl- + H2O2
5-chlorouracil + H2O
show the reaction diagram
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uracil + I- + H2O2
5-iodouracil + H2O
show the reaction diagram
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[2-(2-bromoethyl)cyclopropyl]methanol + tert-butyl hydroperoxide
2-(2-bromoethyl)cyclopropanecarbaldehyde + ?
show the reaction diagram
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0
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[2-(3-bromopropyl)cyclopropyl]methanol + tert-butyl hydroperoxide
2-(3-bromopropyl)cyclopropanecarbaldehyde + ?
show the reaction diagram
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0
?
[2-(hydroxymethyl)cyclopropyl]methyl acetate + tert-butyl hydroperoxide
(2-formylcyclopropyl)methyl acetate + ?
show the reaction diagram
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0
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[3.2.0]hept-2-en-6-one + Br- + H2O2
(1S,2S,3S,5S)-3-bromo-2-hydroxybicyclo[3.2.0]heptan-6-one + H2O
show the reaction diagram
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additional information
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