1.1.3.B5: eugenol oxidase
This is an abbreviated version!
For detailed information about eugenol oxidase, go to the full flat file.
Word Map on EC 1.1.3.B5
Reaction
Synonyms
EUGO, RHA1_ro03282
ECTree
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Substrates Products on EC 1.1.3.B5 - eugenol oxidase
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SUBSTRATE 
PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate)
(Substrate)
LITERATURE
(Substrate)
(Substrate)
COMMENTARY
(Product)
(Product)
LITERATURE
(Product)
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
2,6-dimethoxy-4-allylphenol + O2 + H2O
sinapyl alcohol + H2O2
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?
4-(1-hydroxyethyl)-2-methoxyphenol + O2
1-(4-hydroxy-3-methoxyphenyl)ethan-1-one + 4-[(1S)-1-hydroxyethyl]-2-methoxyphenol + ?
racemic analogue of vanillyl alcohol
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?
4-(4-hydroxyphenyl)butan-2-one + O2
(3E)-4-(4-hydroxyphenyl)but-3-en-2-one + ?
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?
additional information
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enzyme also oxidizes vanillyl alcohol and vanillylamine, reaction of EC 1.1.3.38. Poor substrates: vanillylamine, 4-ethylguaiacol
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additional information
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EUGO can efficiently catalyze the dehydrogenation of various phenolic ketones and the selective oxidation of a racemic 4-(1-hydroxyethyl)-2-methoxyphenol. Very poor substrates: 4-(1,3-dithiolan-2-yl)phenol, capsaicin, (4-hydroxyphenyl)acetonitrile, 3-(4-hydroxyphenyl)propanoic acid, 2-methoxy-4-methylphenol, and 4-(hept-1-enyl)-2-methoxyphenol
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additional information
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EUGO displays a somewhat narrower substrate specificity than vanillyl-alcohol oxidase, EC 1.1.3.38. Although alcohols and 4-allylphenols are good substrates for the enzyme, 4-alkylphenols and ethers are hardly accepted
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