1.1.3.42: prosolanapyrone-II oxidase

This is an abbreviated version!
For detailed information about prosolanapyrone-II oxidase, go to the full flat file.

Word Map on EC 1.1.3.42

Reaction

prosolanapyrone II
+
O2
=
prosolanapyrone III
+
H2O2

Synonyms

Sol5, solanapyrone synthase, SPS

ECTree

     1 Oxidoreductases
         1.1 Acting on the CH-OH group of donors
             1.1.3 With oxygen as acceptor
                1.1.3.42 prosolanapyrone-II oxidase

Systematic Name

Systematic Name on EC 1.1.3.42 - prosolanapyrone-II oxidase

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SYSTEMATIC NAME
IUBMB Comments
prosolanapyrone-II:oxygen 3'-oxidoreductase
The enzyme is involved in the biosynthesis of the phytotoxin solanapyrone by some fungi. The bifunctional enzyme catalyses the oxidation of prosolanapyrone II and the subsequent Diels Alder cycloisomerization of the product prosolanapyrone III to (-)-solanapyrone A (cf. EC 5.5.1.20, prosolanapyrone III cycloisomerase).