1.1.1.312: 2-hydroxy-4-carboxymuconate semialdehyde hemiacetal dehydrogenase
This is an abbreviated version!
For detailed information about 2-hydroxy-4-carboxymuconate semialdehyde hemiacetal dehydrogenase, go to the full flat file.
Word Map on EC 1.1.1.312
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1.1.1.312
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protocatechuate
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2-pyrone-4,6-dicarboxylate
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4,5-dioxygenase
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lignin
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sphingomonas
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ligab
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paucimobilis
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ochraceae
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vanillate
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4,5-cleavage
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hydratase
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syringate
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ecori
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dehydrogenases
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testosteroni
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putida
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nad+
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biotechnology
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4-oxalomesaconate
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comamonas
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oxaloacetate
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industry
- 1.1.1.312
- protocatechuate
- 2-pyrone-4,6-dicarboxylate
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4,5-dioxygenase
- lignin
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sphingomonas
- ligab
- paucimobilis
- ochraceae
- vanillate
-
4,5-cleavage
-
hydratase
- syringate
- ecori
- dehydrogenases
-
testosteroni
- putida
- nad+
- biotechnology
- 4-oxalomesaconate
-
comamonas
- oxaloacetate
- industry
Reaction
Synonyms
2-hydroxy-4-carboxymuconate 6-semialdehyde dehydrogenase, 2-hydroxy-4-carboxymuconate-6-semialdehyde dehydrogenase, 4-carboxy-2-hydroxy-cis,cis-muconate-6-semialdehyde:NADP+ oxidoreductase, 4-carboxy-2-hydroxymuconate-6-semialdehyde dehydrogenase, alpha-hydroxy-gamma-carboxymuconic epsilon-semialdehyde dehydrogenase, CHMS dehydrogenase, CHMS hydrolase, dehydrogenase, 2-hydroxy-4-carboxymuconate 6-semialdehyde, EC 1.2.1.45, PmdC
ECTree
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Substrates Products
Substrates Products on EC 1.1.1.312 - 2-hydroxy-4-carboxymuconate semialdehyde hemiacetal dehydrogenase
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REACTION DIAGRAM
4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NAD+
4-carboxy-2-hydroxy-cis,cis-muconate + NADH
4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NADP+
4-carboxy-2-hydroxy-cis,cis-muconate + NADPH
4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NADP+ + H2O
4-carboxy-2-hydroxy-cis,cis-muconate + NADPH + 2 H+
4-carboxy-2-hydroxymuconate semialdehyde + NADP+
2-pyrone-4,6-dicarboxylic acid + NADPH + H2O
4-carboxy-2-hydroxymuconate semialdehyde hemiacetal + NADP+
2-oxo-2H-pyran-4,6-dicarboxylate + NADPH + H+
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?
4-carboxy-2-hydroxy-cis,cis-muconate + NADH
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?
4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NAD+
4-carboxy-2-hydroxy-cis,cis-muconate + NADH
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NAD+ is less effective than NADP+
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?
4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NAD+
4-carboxy-2-hydroxy-cis,cis-muconate + NADH
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NAD+ is less effective than NADP+
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?
4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NAD+
4-carboxy-2-hydroxy-cis,cis-muconate + NADH
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?
4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NAD+
4-carboxy-2-hydroxy-cis,cis-muconate + NADH
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?
4-carboxy-2-hydroxy-cis,cis-muconate + NADPH
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following intramolecular dehydrogenation to the lactone 2-pyrone-4,6-dicarboxylic acid
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4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NADP+
4-carboxy-2-hydroxy-cis,cis-muconate + NADPH
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following intramolecular dehydrogenation to the lactone 2-pyrone-4,6-dicarboxylic acid, it is not clear whether the lactonization occurs enzymatically or nonenzymatically
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4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NADP+
4-carboxy-2-hydroxy-cis,cis-muconate + NADPH
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or NAD+
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?
4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NADP+
4-carboxy-2-hydroxy-cis,cis-muconate + NADPH
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NAD+ is less effective than NADP+
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-
?
4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NADP+
4-carboxy-2-hydroxy-cis,cis-muconate + NADPH
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NAD+ is less effective than NADP+
-
-
?
4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NADP+
4-carboxy-2-hydroxy-cis,cis-muconate + NADPH
-
-
following intramolecular dehydrogenation to the lactone 2-pyrone-4,6-dicarboxylic acid
?
4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NADP+
4-carboxy-2-hydroxy-cis,cis-muconate + NADPH
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-
following intramolecular dehydrogenation to the lactone 2-pyrone-4,6-dicarboxylic acid
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4-carboxy-2-hydroxy-cis,cis-muconate + NADPH + 2 H+
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?
4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde + NADP+ + H2O
4-carboxy-2-hydroxy-cis,cis-muconate + NADPH + 2 H+
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?
2-pyrone-4,6-dicarboxylic acid + NADPH + H2O
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?
4-carboxy-2-hydroxymuconate semialdehyde + NADP+
2-pyrone-4,6-dicarboxylic acid + NADPH + H2O
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?
2-pyrone-4,6-dicarboxylic acid + NADPH + H+
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protocatechuate + NADP+ + H2O
2-pyrone-4,6-dicarboxylic acid + NADPH + H+
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?
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not: unsubstituted aliphatic or aromatic aldehydes
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additional information
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interaction with Blue Dextran-2000 and related dyes
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additional information
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2-pyrone-4,6-dicarboxylic acid may be a metabolic intermediate in the bacterial metabolism of protocatechuic acid
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?