1.1.1.245: cyclohexanol dehydrogenase
This is an abbreviated version!
For detailed information about cyclohexanol dehydrogenase, go to the full flat file.
Word Map on EC 1.1.1.245
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1.1.1.245
-
cyclohexanone
-
monooxygenase
-
cycloalkanes
-
ncimb
-
cyclopentanone
-
acinetobacter
-
baeyer-villiger
-
alicyclic
-
xanthobacter
-
acidovorax
-
lactones
-
synthesis
- 1.1.1.245
- cyclohexanone
- monooxygenase
-
cycloalkanes
-
ncimb
- cyclopentanone
- acinetobacter
-
baeyer-villiger
-
alicyclic
- xanthobacter
- acidovorax
- lactones
- synthesis
Reaction
Synonyms
alcohol dehydrogenase, CHXON, cyclohexanol dehydrogenase II, dehydrogenase, cyclohexanol, SSADH
ECTree
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Substrates Products
Substrates Products on EC 1.1.1.245 - cyclohexanol dehydrogenase
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REACTION DIAGRAM
1,2-cycloheptanediol + NAD+
cycloheptane-1,2-dione + NADH
-
relative oxidation activity at 25% the rate of cyclohexanol oxidation
-
-
?
1-pentanol + NAD+
n-pentanal + NADH
-
relative activity at 23% the rate of cyclohexanol oxidation
-
-
?
2,3-butanediol + NAD+
? + NADH
-
relative activity at 4% the rate of cyclohexanol oxidation
-
-
?
2,3-dimethylcyclohexanol + NAD+
2,3-dimethylcyclohexanone + NADH
-
relative activity at 78% the rate of cyclohexanol oxidation
-
-
?
2,6-dimethylcyclohexanol + NAD+
2,6-dimethylcyclohexanone + NADH
-
relative activity at 14% the rate of cyclohexanol oxidation
-
-
?
2-butanol + NAD+
2-butanone + NADH
-
relative activity at 44% the rate of cyclohexanol oxidation
-
-
?
2-cyclohexanol + NAD+
2-cyclohexenone + NADH
-
relative oxidation activity at 142% the rate of cyclohexanol oxidation
slow reduction
r
2-hydroxycyclohexanone + NADH
? + NAD+
-
relative activity at 50% the rate of cyclohexanone reduction
-
-
?
2-methyl-1-butanol + NAD+
2-methyl-1-butanal + NADH
-
relative activity at 26% the rate of cyclohexanol oxidation
-
-
?
2-methyl-1-propanol + NAD+
isobutyraldehyde + NADH
-
relative activity at 17% the rate of cyclohexanol oxidation
-
-
?
2-methyl-2-propanol + NAD+
? + NADH
-
relative activity at 16% the rate of cyclohexanol oxidation
-
-
?
2-methylcyclohexanol + NAD+
2-methylcyclohexanone + NADH
-
relative activity at 51% the rate of cyclohexanol oxidation
-
-
?
2-pentanol + NAD+
2-pentanone + NADH
-
relative activity at 43% the rate of cyclohexanol oxidation
-
-
?
3-cyclohexyl-1-propanol + NAD+
3-cyclohexyl-1-propanal + NADH
-
poor substrate
-
-
?
3-hexanol + NAD+
3-hexanone + NADH
-
relative activity at 196% the rate of cyclohexanol oxidation
-
-
?
3-methylcyclohexanol + NAD+
3-methylcyclohexanone + NADH
-
relative activity at 74% the rate of cyclohexanol oxidation
-
-
?
4-heptanol + NAD+
4-heptanone + NADH
-
relative activity at 125% the rate of cyclohexanol oxidation
-
-
?
4-methylcyclohexanol + NAD+
4-methylcyclohexanone + NADH
-
relative activity at 66% the rate of cyclohexanol oxidation
-
-
?
cis-cyclopentane-1,2-diol + NAD+
? + NADH
-
relative activity at 27% the rate of cyclohexanol oxidation
-
-
?
cycloheptanone + NADH
cycloheptanol + NAD+
-
relative activity at 10% the rate of cyclohexanone reduction
-
-
?
cyclooctanol + NAD+
cyclooctanone + NADH
-
relative activity at 500% the rate of cyclohexanol oxidation
-
-
?
ethane-1,2-diol + NAD+
glyoxal + NADH
-
relative activity at 5% the rate of cyclohexanol oxidation
-
-
?
hexane-1,2-diol + NAD+
2-oxohexanal + NADH
-
relative activity at 84% the rate of cyclohexanol oxidation
-
-
?
hexane-1,6-diol + NAD+
hexanedial + NADH
-
relative activity at 21% the rate of cyclohexanol oxidation
-
-
?
propane-1,2-diol + NAD+
methylglyoxal + NADH
-
relative activity at 30% the rate of cyclohexanol oxidation
-
-
?
propane-1,3-diol + NAD+
? + NADH
-
relative activity at 7% the rate of cyclohexanol oxidation
-
-
?
trans-cyclohexane-1,2-diol + NAD+
cyclohexane-1,2-dione + NADH + H+
-
-
-
-
?
trans-cyclopentane-1,2-diol + NAD+
? + NADH
-
relative activity at 114% the rate of cyclohexanol oxidation
-
-
?
1-butanol + NAD+
butanal + NADH
-
relative activity at 20% the rate of cyclohexanol oxidation
-
-
?
1-heptanol + NAD+
heptanal + NADH
-
relative oxidation activity at 32% the rate of cyclohexanol oxidation
-
-
?
hexanal + NADH
-
relative oxidation activity at 7% the rate of cyclohexanol oxidation
-
-
?
1-hexanol + NAD+
hexanal + NADH
-
relative oxidation activity at 21% the rate of cyclohexanol oxidation
-
-
?
propionaldehyde + NADH
-
relative activity at 20% the rate of cyclohexanol oxidation
-
-
?
acetone + NADH
-
relative activity at 19% the rate of cyclohexanol oxidation
-
-
?
2-propanol + NAD+
acetone + NADH
-
relative activity at 17% the rate of cyclohexanol oxidation
-
-
?
cyclohexane-1,2-dione + NADH
-
relative oxidation activity at 43% the rate of cyclohexanol oxidation
-
-
?
cyclohexan-1,2-diol + NAD+
cyclohexane-1,2-dione + NADH
-
relative oxidation activity at 15% the rate of cyclohexanol oxidation
slow reduction
r
cyclohexan-1,2-diol + NAD+
cyclohexane-1,2-dione + NADH
-
relative oxidation activity of cis-isomer at 28% the rate of cyclohexanol oxidation
-
-
?
cyclohexan-1,2-diol + NAD+
cyclohexane-1,2-dione + NADH
-
relative oxidation activity of cis/trans mixture at 123% the rate of cyclohexanol oxidation
-
-
?
cyclohexan-1,2-diol + NAD+
cyclohexane-1,2-dione + NADH
-
relative oxidation activity of trans-isomer at 146% the rate of cyclohexanol oxidation
-
-
?
cyclohexan-1,2-diol + NAD+
cyclohexane-1,2-dione + NADH
-
relative oxidation activity of cis-isomer at 28% the rate of cyclohexanol oxidation
-
-
?
cyclohexane-1,3-dione + NADH
-
relative oxidation activity at 96% the rate of cyclohexanol oxidation
-
-
?
cyclohexane-1,3-diol + NAD+
cyclohexane-1,3-dione + NADH
-
relative oxidation activity at 14% the rate of cyclohexanol oxidation
slow reduction
r
cyclohexane-1,3-diol + NAD+
cyclohexane-1,3-dione + NADH
-
relative oxidation activity at 28% the rate of cyclohexanol oxidation
-
-
?
cyclohexane-1,4-dione + NADH
-
relative oxidation activity at 91% the rate of cyclohexanol oxidation
-
-
?
cyclohexane-1,4-diol + NAD+
cyclohexane-1,4-dione + NADH
-
relative oxidation activity at 36% the rate of cyclohexanol oxidation
relative reduction activity at 240% the rate of cyclohexanone reduction
r
cyclohexane-1,4-diol + NAD+
cyclohexane-1,4-dione + NADH
-
relative oxidation activity at 22% the rate of cyclohexanol oxidation
-
-
?
cyclohexanol + NAD+
cyclohexanone + NADH
-
metabolism of cyclohexane
-
r
cyclohexanol + NAD+
cyclohexanone + NADH + H+
-
temperature-induced conformational change is associated with the flexible loops directly involved in the substrate and coenzyme binding
-
-
?
cyclopentanone + NADH
-
relative oxidation activity at 232% the rate of cyclohexanol oxidation
-
-
?
cyclopentanol + NAD+
cyclopentanone + NADH
-
-
relative reduction activity at 4% the rate of cyclohexanone reduction
r
cyclopentanol + NAD+
cyclopentanone + NADH
-
relative oxidation activity at 77% the rate of cyclohexanol oxidation
-
-
?
cyclopentanol + NAD+
cyclopentanone + NADH
-
relative oxidation activity at 77% the rate of cyclohexanol oxidation
-
-
?
acetaldehyde + NADH
-
relative activity at 20% the rate of cyclohexanol oxidation
-
-
?
ethanol + NAD+
acetaldehyde + NADH
-
relative activity at 20% the rate of cyclohexanol oxidation
-
-
?
formaldehyde + NADH + H+
-
relative activity at 2% the rate of cyclohexanol oxidation
-
-
?
methanol + NAD+
formaldehyde + NADH + H+
-
relative activity at 2% the rate of cyclohexanol oxidation
-
-
?
additional information
-
-
2-hydroxycyclohexanone, 1,3,5-trihydroxycyclohexane, menthol, ethanol, 1-propanol, 1-butanol and 1-pentanol are not oxidized with NAD+
2-cyclopentenone, 1,3-cyclohexanedione, 1,3-cyclopentanedione and 5-oxocapronate are not reduced with NADH
?
additional information
additional information
-
-
cyclohexane-1,2-dione is not oxidized with NAD+
-
-
?