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Literature summary for 4.1.2.13 extracted from

  • Li, Z.; Cai, L.; Wei, M.; Wang, P.G.
    One-pot four-enzyme synthesis of ketoses with fructose 1,6-bisphosphate aldolases from Staphylococcus carnosus and rabbit muscle (2012), Carbohydr. Res., 357, 143-146.
    View publication on PubMedView publication on EuropePMC

Application

Application Comment Organism
synthesis enzyme FruA has a flexible substrate specificity and accepts various aldehydes. It is applcable for synthesis of a number of ketoses using simple aliphatic aldehydes as acceptors in a one-pot reaction system. The yields are quite similar for reactions of which acetaldehyde, propionaldehyde, and butyraldehyde are acceptors Staphylococcus carnosus

Organism

Organism UniProt Comment Textmining
Oryctolagus cuniculus
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Staphylococcus carnosus
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Source Tissue

Source Tissue Comment Organism Textmining
muscle
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Oryctolagus cuniculus
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
2 acetaldehyde
-
Oryctolagus cuniculus 5-deoxy-D-threo-2-pentulose yield 29% ?
2 acetaldehyde
-
Staphylococcus carnosus 5-deoxy-D-threo-2-pentulose yield 33% ?
2 butyraldehyde
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Oryctolagus cuniculus 5,6,7-trideoxy-D-threo-2-heptulose yield 38% ?
2 butyraldehyde
-
Staphylococcus carnosus 5,6,7-trideoxy-D-threo-2-heptulose yield 40% ?
2 D-glyceraldehyde
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Staphylococcus carnosus D-fructose yield 60% ?
2 pentanaldehyde
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Oryctolagus cuniculus 5,6,7,8-tetradeoxy-D-threo-2-octulose yield 13% ?
2 pentanaldehyde
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Staphylococcus carnosus 5,6,7,8-tetradeoxy-D-threo-2-octulose yield 23% ?
2 propionaldehyde
-
Oryctolagus cuniculus 5,6-dideoxy-D-threo-2-hexulose yield 34% ?
2 propionaldehyde
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Staphylococcus carnosus 5,6-dideoxy-D-threo-2-hexulose yield 37% ?
L-glyceraldehyde
-
Staphylococcus carnosus L-sorbose yield 28% ?
additional information enzyme FruA has a flexible substrate specificity and accepts various aldehydes. It is applcable for synthesis of a number of ketoses using simple aliphatic aldehydes as acceptors in a one-pot reaction system. The yields are quite similar for reactions of which acetaldehyde, propionaldehyde, and butyraldehyde are acceptors Staphylococcus carnosus ?
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