Application | Comment | Organism |
---|---|---|
synthesis | one-pot synthesis of di-demethylasterriquinone D from L-tryptophan and phenylpyruvic acid by use of enzymes TdiA and TdiD | Aspergillus nidulans |
Cloned (Comment) | Organism |
---|---|
expression in Escherichia coli | Aspergillus nidulans |
KM Value [mM] | KM Value Maximum [mM] | Substrate | Comment | Organism | Structure |
---|---|---|---|---|---|
1.43 | - |
phenylpyruvate | pH 7.0, 48°C | Aspergillus nidulans | |
3.02 | - |
L-tryptophan | pH 7.0, 48°C | Aspergillus nidulans |
Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
---|---|---|---|---|---|---|
additional information | Aspergillus nidulans | catalyzes the first enzymatic step specific to the metabolic pathway toward terrequinone A | ? | - |
? |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Aspergillus nidulans | A7XRY8 | - |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
L-tryptophan + 4-hydroxyphenylpyruvate | 15% of the activity with phenylpyruvate | Aspergillus nidulans | 3-indole-2-oxopropanoate + ? | - |
? | |
L-tryptophan + phenylpyruvate | - |
Aspergillus nidulans | 3-indole-2-oxopropanoate + L-phenylalanine | - |
? | |
additional information | catalyzes the first enzymatic step specific to the metabolic pathway toward terrequinone A | Aspergillus nidulans | ? | - |
? | |
additional information | no amino acceptor substrate: pyruvic acid, 2-oxoglutaric acid, 2-oxo-butyric acid, 2-oxo-valeric acid | Aspergillus nidulans | ? | - |
? |
Temperature Optimum [°C] | Temperature Optimum Maximum [°C] | Comment | Organism |
---|---|---|---|
48 | - |
- |
Aspergillus nidulans |
Turnover Number Minimum [1/s] | Turnover Number Maximum [1/s] | Substrate | Comment | Organism | Structure |
---|---|---|---|---|---|
9.1 | - |
phenylpyruvate | pH 7.0, 48°C | Aspergillus nidulans | |
19.3 | - |
L-tryptophan | pH 7.0, 48°C | Aspergillus nidulans |
pH Optimum Minimum | pH Optimum Maximum | Comment | Organism |
---|---|---|---|
7 | - |
- |
Aspergillus nidulans |