Crystallization (Comment) | Organism |
---|---|
crystal structure of (3,5-dimethyltrispyrazol-1-yl)borate MoO(2-mercaptobenzyl alcohol), the first oxomolybdenum monothiolate to possess an Oax-Mo-Sthiolate-C dihedral angle of ca. 90° | synthetic construct |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
synthetic construct | - |
- |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
additional information | Oax-Mo-Sthiolate-C dihedral angles near 90° effectively eliminate covalency contributions to the Mo(xy) redox orbital from the thiolate sulfur. The Oax-Mo-Sthiolate-C dihedral angle is shown to have a pronounced effect on the relative intensity ratios of the XAS spin-allowed S(1s)fSv(p) + Mo-(xy) and S(1s)fSv(p) + Mo(xz,yz) transitions | synthetic construct | ? | - |
? |