Application | Comment | Organism |
---|---|---|
analysis | in situ generation of oxo-sulfidobis(dithiolene)tungsten(VI) complexes that model the proposed active-site structure for the AOR family of tungsten enzymes. The complexes are characterized by UV-vis, electrospray ionization mass spectrometry, IR, and resonance Raman spectroscopies and are found to mimic the coordination environment including the W=E (E=O, S) bond strengths and hydrolytic reactions of the tungsten center of the AOR family | synthetic construct |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
synthetic construct | - |
- |
- |
Synonyms | Comment | Organism |
---|---|---|
AOR | - |
synthetic construct |
Cofactor | Comment | Organism | Structure |
---|---|---|---|
additional information | the active tungsten center is hydrolyzed to the inactive dioxotungsten(VI) center ([WVIO2]2+) in the absence of sulfide | synthetic construct |