Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
---|---|---|---|---|---|---|
tryptophan + FADH2 + Cl- + O2 + H+ | Pseudomonas fluorescens | chlorination of its natural substrate tryptophan exclusively at the 7-position, a position at which direct chemical chlorination is not possible | 7-chloro-tryptophan + FAD + H2O | - |
? | |
tryptophan + FADH2 + Cl- + O2 + H+ | Pseudomonas fluorescens BL915 | chlorination of its natural substrate tryptophan exclusively at the 7-position, a position at which direct chemical chlorination is not possible | 7-chloro-tryptophan + FAD + H2O | - |
? |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Pseudomonas fluorescens | Q9RPG3 | BL915 | - |
Pseudomonas fluorescens BL915 | Q9RPG3 | BL915 | - |
Purification (Comment) | Organism |
---|---|
- |
Pseudomonas fluorescens |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
additional information | Trp 7-hal can accept a number of different tryptophan, indole, and phenylpyrrole derivatives (e.g. 3-(2'-aminophenyl)pyrrole or monodechloroaminopyrrolnitrin), but only tryptophan is regioselectively chlorinated in the 7-position of the indole ring. With all the other compounds, the reaction proceeds with a relaxed regioselectivity | Pseudomonas fluorescens | ? | - |
? | |
additional information | Trp 7-hal can accept a number of different tryptophan, indole, and phenylpyrrole derivatives (e.g. 3-(2'-aminophenyl)pyrrole or monodechloroaminopyrrolnitrin), but only tryptophan is regioselectively chlorinated in the 7-position of the indole ring. With all the other compounds, the reaction proceeds with a relaxed regioselectivity | Pseudomonas fluorescens BL915 | ? | - |
? | |
tryptophan + FADH2 + Cl- + O2 + H+ | - |
Pseudomonas fluorescens | 7-chloro-tryptophan + FAD + H2O | - |
? | |
tryptophan + FADH2 + Cl- + O2 + H+ | chlorination of its natural substrate tryptophan exclusively at the 7-position, a position at which direct chemical chlorination is not possible | Pseudomonas fluorescens | 7-chloro-tryptophan + FAD + H2O | - |
? | |
tryptophan + FADH2 + Cl- + O2 + H+ | - |
Pseudomonas fluorescens BL915 | 7-chloro-tryptophan + FAD + H2O | - |
? | |
tryptophan + FADH2 + Cl- + O2 + H+ | chlorination of its natural substrate tryptophan exclusively at the 7-position, a position at which direct chemical chlorination is not possible | Pseudomonas fluorescens BL915 | 7-chloro-tryptophan + FAD + H2O | - |
? |
Synonyms | Comment | Organism |
---|---|---|
Trp 7-hal | - |
Pseudomonas fluorescens |