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Literature summary for 1.14.14.21 extracted from

  • Kobayashi, M.; Onaka, T.; Ishii, Y.; Konishi, J.; Takaki, M.; Okada, H.; Ohta, Y.; Koizumi, K.; Suzuki, M.
    Desulfurization of alkylated forms of both dibenzothiophene and benzothiophene by a single bacterial strain (2000), FEMS Microbiol. Lett., 187, 123-126.
    View publication on PubMed
Search for more literature for 1.14.14.21

Cloned(Commentary)

Cloned (Comment) Organism
gene dszC, DNA and amino acid sequence determination and analysis, cloning and recombinant expression in Escherichia coli strain JM109 Rhodococcus erythropolis

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
2,8-dimethyldibenzothiophene + 2 FMNH2 + 2 O2 Rhodococcus erythropolis
-
 2,8-dimethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
2,8-dimethyldibenzothiophene + 2 FMNH2 + 2 O2 Rhodococcus erythropolis KA2-5-1
-
 2,8-dimethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
2-ethyldibenzothiophene + 2 FMNH2 + 2 O2 Rhodococcus erythropolis
-
 2-ethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
2-ethyldibenzothiophene + 2 FMNH2 + 2 O2 Rhodococcus erythropolis KA2-5-1
-
 2-ethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
3,4,6,7-tetramethyldibenzothiophene + 2 FMNH2 + 2 O2 Rhodococcus erythropolis
-
 3,4,6,7-tetramethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
3,4,6,7-tetramethyldibenzothiophene + 2 FMNH2 + 2 O2 Rhodococcus erythropolis KA2-5-1
-
 3,4,6,7-tetramethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
3,4,6-trimethyldibenzothiophene + 2 FMNH2 + 2 O2 Rhodococcus erythropolis
-
 3,4,6-trimethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
3-ethyldibenzothiophene + 2 FMNH2 + 2 O2 Rhodococcus erythropolis
-
 3-ethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
4,6-dimethyldibenzothiophene + 2 FMNH2 + 2 O2 Rhodococcus erythropolis
-
 4,6-dimethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
4-methyldibenzothiophene + 2 FMNH2 + 2 O2 Rhodococcus erythropolis
-
 4-methyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
benzothiophene + 2 FMNH2 + 2 O2 Rhodococcus erythropolis
-
 benzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
dibenzothiophene + 2 FMNH2 + 2 O2 Rhodococcus erythropolis best substrate dibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
additional information Rhodococcus erythropolis strain KA2-5-1 desulfurizes a variety of alkyl dibenzothiophenes through the specific cleavage of their C-S bonds. In addition, strain KA2-5-1 also attacks alkyl benzothiophenes in a C-S-bond-targeted fashion, substrate specificity overview ?
-
 ?
additional information Rhodococcus erythropolis KA2-5-1 strain KA2-5-1 desulfurizes a variety of alkyl dibenzothiophenes through the specific cleavage of their C-S bonds. In addition, strain KA2-5-1 also attacks alkyl benzothiophenes in a C-S-bond-targeted fashion, substrate specificity overview ?
-
 ?

Organism

Organism UniProt Comment Textmining
Rhodococcus erythropolis A0SWL2 strain IGTS8, differs only in two positions from strain KA2-5-1 sequence; gene dszC
-
Rhodococcus erythropolis KA2-5-1 A0SWL2 strain IGTS8, differs only in two positions from strain KA2-5-1 sequence; gene dszC
-

Source Tissue

Source Tissue Comment Organism Textmining
cell culture growth on dibenzothiophene as sole sulfur source, no or poor growth of strain KA2-5-1 with benzothiophene and various alkyl benzothiophenes, overview Rhodococcus erythropolis
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
2,8-dimethyldibenzothiophene + 2 FMNH2 + 2 O2
-
 Rhodococcus erythropolis 2,8-dimethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
2,8-dimethyldibenzothiophene + 2 FMNH2 + 2 O2
-
 Rhodococcus erythropolis KA2-5-1 2,8-dimethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
2-ethyldibenzothiophene + 2 FMNH2 + 2 O2
-
 Rhodococcus erythropolis 2-ethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
2-ethyldibenzothiophene + 2 FMNH2 + 2 O2
-
 Rhodococcus erythropolis KA2-5-1 2-ethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
3,4,6,7-tetramethyldibenzothiophene + 2 FMNH2 + 2 O2
-
 Rhodococcus erythropolis 3,4,6,7-tetramethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
3,4,6,7-tetramethyldibenzothiophene + 2 FMNH2 + 2 O2
-
 Rhodococcus erythropolis KA2-5-1 3,4,6,7-tetramethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
3,4,6-trimethyldibenzothiophene + 2 FMNH2 + 2 O2
-
 Rhodococcus erythropolis 3,4,6-trimethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
3-ethyldibenzothiophene + 2 FMNH2 + 2 O2
-
 Rhodococcus erythropolis 3-ethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
4,6-dimethyldibenzothiophene + 2 FMNH2 + 2 O2
-
 Rhodococcus erythropolis 4,6-dimethyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
4-methyldibenzothiophene + 2 FMNH2 + 2 O2
-
 Rhodococcus erythropolis 4-methyldibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
benzothiophene + 2 FMNH2 + 2 O2
-
 Rhodococcus erythropolis benzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
dibenzothiophene + 2 FMNH2 + 2 O2
-
 Rhodococcus erythropolis dibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
dibenzothiophene + 2 FMNH2 + 2 O2 best substrate Rhodococcus erythropolis dibenzothiophene-5,5-dioxide + 2 FMN + 2 H2O
-
 ?
additional information strain KA2-5-1 desulfurizes a variety of alkyl dibenzothiophenes through the specific cleavage of their C-S bonds. In addition, strain KA2-5-1 also attacks alkyl benzothiophenes in a C-S-bond-targeted fashion, substrate specificity overview Rhodococcus erythropolis ?
-
 ?
additional information the purified monooxygenase, encoded by dszC of KA2-5-1, converts benzothiophene and dibenzothiophene into benzothiophene sulfone and dibenzothiophene sulfone, respectively, with the aid of an NADH-dependent oxidoreductase, substrate specificity overview Rhodococcus erythropolis ?
-
 ?
additional information strain KA2-5-1 desulfurizes a variety of alkyl dibenzothiophenes through the specific cleavage of their C-S bonds. In addition, strain KA2-5-1 also attacks alkyl benzothiophenes in a C-S-bond-targeted fashion, substrate specificity overview Rhodococcus erythropolis KA2-5-1 ?
-
 ?
additional information the purified monooxygenase, encoded by dszC of KA2-5-1, converts benzothiophene and dibenzothiophene into benzothiophene sulfone and dibenzothiophene sulfone, respectively, with the aid of an NADH-dependent oxidoreductase, substrate specificity overview Rhodococcus erythropolis KA2-5-1 ?
-
 ?