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Literature summary for 1.14.13.22 extracted from

  • Schwab, J.M.; Li, W.; Thomas, L.P.
    Cyclohexanone oxygenase: stereochemistry, enantioselectivity, and regioselectivity of an enzyme-catalyzed Baeyer-Villiger reaction (1983), J. Am. Chem. Soc., 105, 4800-4808.
No PubMed abstract available

Organism

Organism UniProt Comment Textmining
Acinetobacter sp.
-
NCIB 9871
-

Purification (Commentary)

Purification (Comment) Organism
-
Acinetobacter sp.

Reaction

Reaction Comment Organism Reaction ID
cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O stereochemistry Acinetobacter sp.
cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O mechanistic study Acinetobacter sp.
cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O enantioselectivity Acinetobacter sp.
cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O regioselectivity Acinetobacter sp.

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
2-methylcyclohexanone + NADPH + O2
-
Acinetobacter sp. 1-oxa-2-oxo-3-methylcycloheptane + NADP+ + H2O
-
?
cyclohexanone + NADPH + O2
-
Acinetobacter sp. 6-hexanolide + NADP+ + H2O
-
?

Cofactor

Cofactor Comment Organism Structure
NADPH
-
Acinetobacter sp.