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Literature summary for 1.12.99.6 extracted from
- Nitrosyl derivatives of diiron(I) dithiolates mimic the structure and Lewis acidity of the [FeFe]-hydrogenase active site (2008), J. Am. Chem. Soc., 130, 12021-12030.
Activating Compound
| Activating Compound | Comment | Organism | Structure |
|---|---|---|---|
| additional information | nitrosyl complexes reduce at potentials that are ca. 1 V milder than their carbonyl counterparts, NO+ forms diiron dithiolates that are not isostructural with the corresponding carbonyl complexes and that display enhanced Lewis acidity | synthetic construct |
Inhibitors
| Inhibitors | Comment | Organism | Structure |
|---|---|---|---|
| CO | the bis(PMe3) nitrosyl complexes readily undergo CO substitution to give the (PMe3)3 derivatives | synthetic construct |  |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| synthetic construct | - |
- |
- |
Synonyms
| Synonyms | Comment | Organism |
|---|---|---|
| [FeFe]-hydrogenase | - |
synthetic construct |
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Release 2023.1 (January 2023)
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