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Literature summary for 1.11.1.B2 extracted from

  • Pasta, P.; Carrea, G.; Colonna, S.; Gaggero, N.
    Effects of chloride on the kinetics and stereochemistry of chloroperoxidase catalyzed oxidation of sulfides (1994), Biochim. Biophys. Acta, 1209, 203-208.
    View publication on PubMed

Organism

Organism UniProt Comment Textmining
Leptoxyphium fumago
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
methyl p-tolyl sulfide + H2O2 in absence of Cl- the oxidation is enantioselective and an oxygen atom of H2O2 is incorporated in the sulfoxide, in the presence of Cl- the oxidation is not enantioselective and there is no incorporation of oxygen from H2O2. The sulfide oxidation takes place through an enzyme-generated freely dissociable oxidized halogen intermediate formed by the interaction of enzyme-OCl- with Cl- Leptoxyphium fumago p-tolyl methyl sulfoxide
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