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Literature summary for 1.1.99.30 extracted from
- Proteus mirabilis dehydrogenates aldonates and aldarates with an (R)-configured alpha-carbon atom to the corresponding 2-oxocarboxylates (1994), Bioorg. Med. Chem., 2, 483-491.
KM Value [mM]
| KM Value [mM] | KM Value Maximum [mM] | Substrate | Comment | Organism | Structure |
|---|---|---|---|---|---|
| 0.025 | - |
carboxamido-methyl viologen | pH 8.5, 38°C | Proteus mirabilis |  |
| 0.042 | - |
benzyl viologen | pH 8.5, 38°C | Proteus mirabilis | |
| 0.19 | - |
oxidized antraquinone-2,6-disulfonate | pH 8.5, 38°C | Proteus mirabilis | |
| 0.3 | - |
D-ribonate | pH 8.5, 38°C | Proteus mirabilis | |
| 0.42 | - |
galactarate | pH 8.5, 38°C | Proteus mirabilis | |
| 0.48 | - |
D-galactonate | pH 8.5, 38°C | Proteus mirabilis | |
| 0.64 | - |
6-phospho-D-gluconate | pH 8.5, 38°C | Proteus mirabilis | |
| 0.64 | - |
D-gulonate | pH 8.5, 38°C | Proteus mirabilis | |
| 0.66 | - |
Lactobionate | pH 8.5, 38°C | Proteus mirabilis | |
| 0.68 | - |
D-lactate | pH 8.5, 38°C | Proteus mirabilis | |
| 0.92 | - |
L-mannonate | pH 8.5, 38°C | Proteus mirabilis | |
| 0.98 | - |
D-gluconate | pH 8.5, 38°C | Proteus mirabilis | |
| 1.27 | - |
D-xylonate | pH 8.5, 38°C | Proteus mirabilis | |
| 1.46 | - |
L-arabinuronate | pH 8.5, 38°C | Proteus mirabilis | |
| 1.68 | - |
D-glucarate | pH 8.5, 38°C | Proteus mirabilis | |
| 2.03 | - |
L-arabinoic acid | pH 8.5, 38°C | Proteus mirabilis | |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Proteus mirabilis | - |
- |
- |
Reaction
| Reaction | Comment | Organism | Reaction ID |
|---|---|---|---|
| a (2R)-hydroxy-carboxylate + acceptor = a 2-oxo-carboxylate + reduced acceptor | aldonates and aldarates with an (R)-configured alpha-carbon atom are converted to the corresponding 2-oxocarboxylates | Proteus mirabilis |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| 6-phospho-D-gluconate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | 6-phospho-D-arabino-hex-2-ulosonate + reduced anthraquinone-2,6-disulfonate | - |
r | |
| 6-phospho-D-gluconate + oxidized benzyl viologen | - |
Proteus mirabilis | 6-phospho-D-arabino-hex-2-ulosonate + reduced benzyl viologen | - |
r | |
| 6-phospho-D-gluconate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | 6-phospho-D-arabino-hex-2-ulosonate + reduced carboxamido-methyl viologen | - |
r | |
| D-galactonate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | D-lyxo-hex-2-ulosonate + reduced anthraquinone-2,6-disulfonate | - |
r | |
| D-galactonate + oxidized benzyl viologen | - |
Proteus mirabilis | D-lyxo-hex-2-ulosonate + reduced benzyl viologen | - |
r | |
| D-galactonate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | D-lyxo-hex-2-ulosonate + reduced carboxamido-methyl viologen | - |
r | |
| D-glucarate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | 2-oxo-D-glucarate + reduced anthraquinone-2,6-disulfonate | - |
r | |
| D-glucarate + oxidized benzyl viologen | - |
Proteus mirabilis | 2-oxo-D-glucarate + reduced benzyl viologen | - |
r | |
| D-glucarate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | 2-oxo-D-glucarate + reduced carboxamido-methyl viologen | - |
r | |
| D-gluconate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | D-arabino-hex-2-ulosonate + reduced anthraquinone-2,6-disulfonate | - |
r | |
| D-gluconate + oxidized benzyl viologen | - |
Proteus mirabilis | D-arabino-hex-2-ulosonate + reduced benzyl viologen | - |
r | |
| D-gluconate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | D-arabino-hex-2-ulosonate + reduced carboxamido-methyl viologen | - |
r | |
| D-gulonate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | D-arabino-hex-2-ulosonate + reduced anthraquinone-2,6-disulfonate | - |
r | |
| D-gulonate + oxidized benzyl viologen | - |
Proteus mirabilis | D-arabino-hex-2-ulosonate + reduced benzyl viologen | - |
r | |
| D-gulonate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | D-arabino-hex-2-ulosonate + reduced carboxamido-methyl viologen | - |
r | |
| D-lactate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | pyruvate + reduced anthraquinone-2,6-disulfonate | - |
r | |
| D-lactate + oxidized benzyl viologen | - |
Proteus mirabilis | pyruvate + reduced benzyl viologen | - |
r | |
| D-lactate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | pyruvate + reduced carboxamido-methyl viologen | - |
r | |
| D-ribonate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | D-erythro-pent-2-ulosonate + reduced anthraquinone-2,6-disulfonate | - |
r | |
| D-ribonate + oxidized benzyl viologen | - |
Proteus mirabilis | D-erythro-pent-2-ulosonate + reduced benzyl viologen | - |
r | |
| D-ribonate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | D-erythro-pent-2-ulosonate + reduced carboxamido-methyl viologen | - |
r | |
| D-xylonate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | D-threo-pent-2-ulosonate + reduced anthraquinone-2,6-disulfonate | - |
r | |
| D-xylonate + oxidized benzyl viologen | - |
Proteus mirabilis | D-threo-pent-2-ulosonate + reduced benzyl viologen | - |
r | |
| D-xylonate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | D-threo-pent-2-ulosonate + reduced carboxamido-methyl viologen | - |
r | |
| dimethylsulfoxide + oxidized antraquinone-2,6-disulfonate | - |
Proteus mirabilis | dimethylsulfide + reduced antraquinone-2,6-disulfonate | - |
r | |
| galactarate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | 2-oxogalactarate + reduced anthraquinone-2,6-disulfonate | - |
r | |
| galactarate + oxidized benzyl viologen | - |
Proteus mirabilis | 2-oxogalactarate + reduced benzyl viologen | - |
r | |
| galactarate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | 2-oxogalactarate + reduced carboxamido-methyl viologen | - |
r | |
| L-arabinonate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | L-erythro-pent-2-ulosonate + reduced anthraquinone-2,6-disulfonate | - |
r | |
| L-arabinonate + oxidized benzyl viologen | - |
Proteus mirabilis | L-erythro-pent-2-ulosonate + reduced benzyl viologen | - |
r | |
| L-arabinonate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | L-erythro-pent-2-ulosonate + reduced carboxamido-methyl viologen | - |
r | |
| L-arabinuronate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | ? + reduced anthraquinone-2,6-disulfonate | - |
r | |
| L-arabinuronate + oxidized benzyl viologen | - |
Proteus mirabilis | ? + reduced benzyl viologen | - |
r | |
| L-arabinuronate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | ? + reduced carboxamido-methyl viologen | - |
r | |
| L-mannonate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | L-arabino-hex-2-ulosonate + reduced anthraquinone-2,6-disulfonate | - |
r | |
| L-mannonate + oxidized benzyl viologen | - |
Proteus mirabilis | L-arabino-hex-2-ulosonate + reduced benzyl viologen | - |
r | |
| L-mannonate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | L-arabino-hex-2-ulosonate + reduced carboxamido-methyl viologen | - |
r | |
| lactobionate + oxidized anthraquinone-2,6-disulfonate | - |
Proteus mirabilis | 4-O-(beta-D-galactopyranosido)-D-arabino-hex-2-ulosonate + reduced anthraquinone-2,6-disulfonate | - |
r | |
| lactobionate + oxidized benzyl viologen | - |
Proteus mirabilis | 4-O-(beta-D-galactopyranosido)-D-arabino-hex-2-ulosonate + reduced benzyl viologen | - |
r | |
| lactobionate + oxidized carboxamido-methyl viologen | - |
Proteus mirabilis | 4-O-(beta-D-galactopyranosido)-D-arabino-hex-2-ulosonate + reduced carboxamido-methyl viologen | - |
r | |
| additional information | product determination, stereochemistry and molecule conformations, products appear in pyranose, furanose or lactone form, overview | Proteus mirabilis | ? | - |
? | |
| phenylpyruvate + reduced carbamoylmethyl viologen | - |
Proteus mirabilis | (2R)-phenyllactate + oxidized carbamoylmethyl viologen | - |
? | |
Synonyms
| Synonyms | Comment | Organism |
|---|---|---|
| (2R)-hydroxycarboxlate viologen oxidoreductase | - |
Proteus mirabilis |
Temperature Optimum [°C]
| Temperature Optimum [°C] | Temperature Optimum Maximum [°C] | Comment | Organism |
|---|---|---|---|
| 25 | - |
assay at | Proteus mirabilis |
pH Optimum
| pH Optimum Minimum | pH Optimum Maximum | Comment | Organism |
|---|---|---|---|
| 8.5 | - |
assay at | Proteus mirabilis |
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Release 2023.1 (January 2023)
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