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Literature summary for 1.1.3.20 extracted from
- Oxidation of fatty alcohol in the cotyledons of jojoba seedlings (1979), Arch. Biochem. Biophys., 194, 422-430.
Inhibitors
| Inhibitors | Comment | Organism | Structure |
|---|---|---|---|
| additional information | no inhibitor: cyanide | Simmondsia chinensis | |
| p-chloromercuribenzoate | 70% loss of activity at 0.1 mM, completely reversible with dithiothreitol | Simmondsia chinensis |  |
Localization
| Localization | Comment | Organism | GeneOntology No. | Textmining |
|---|---|---|---|---|
| glyoxysome | - |
Simmondsia chinensis | 9514 | - |
| membrane | - |
Simmondsia chinensis | 16020 | - |
| oil body | - |
Simmondsia chinensis | - |
- |
Natural Substrates/ Products (Substrates)
| Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| long-chain alcohol + O2 | Simmondsia chinensis | reaction in wax ester catabolism in the storage wax bodies of jojoba plant during germination | ? | - |
? | |
| long-chain alcohol + O2 | Simmondsia chinensis | monounsaturated long-chain alcohols | ? | - |
? | |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Simmondsia chinensis | - |
jojoba | - |
Reaction
| Reaction | Comment | Organism | Reaction ID |
|---|---|---|---|
| a long-chain alcohol + O2 = a long-chain aldehyde + H2O2 | 2 long-chain alcohol + O2 = 2 long-chain aldehyde + 2 H2O2 | Simmondsia chinensis |
Storage Stability
| Storage Stability | Organism |
|---|---|
| freezing overnight leads to 50% loss of activity | Simmondsia chinensis |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| 1-docosanol + O2 | i.e. behenyl alcohol, poor substrate | Simmondsia chinensis | docosanal + H2O2 | - |
? | |
| 1-eicosanol + O2 | i.e. arachidyl alcohol, poor substrate | Simmondsia chinensis | eicosanal + H2O2 | - |
? | |
| 1-tetradecanol + O2 | - |
Simmondsia chinensis | tetradecanal + H2O2 | - |
? | |
| cis-11-eicosenol + O2 | higher oxidation rate than saturated analog | Simmondsia chinensis | cis-11-eicosenal + H2O2 | - |
? | |
| decanol + O2 | - |
Simmondsia chinensis | decanal + H2O2 | - |
? | |
| docosenol + O2 | higher oxidation rate than saturated analog | Simmondsia chinensis | docosenal + H2O2 | - |
? | |
| dodecanol + O2 | i.e. lauryl alcohol, preferred substrate | Simmondsia chinensis | dodecanal + H2O2 | - |
? | |
| hexadecanol + O2 | - |
Simmondsia chinensis | hexadecanal + H2O2 | - |
? | |
| long-chain alcohol + O2 | reaction in wax ester catabolism in the storage wax bodies of jojoba plant during germination | Simmondsia chinensis | ? | - |
? | |
| long-chain alcohol + O2 | monounsaturated long-chain alcohols | Simmondsia chinensis | ? | - |
? | |
| additional information | no substrates: ethanol, palmitic acid | Simmondsia chinensis | ? | - |
? | |
| octadecanol + O2 | - |
Simmondsia chinensis | octadecanal + H2O2 | - |
? | |
Temperature Stability [°C]
| Temperature Stability Minimum [°C] | Temperature Stability Maximum [°C] | Comment | Organism |
|---|---|---|---|
| 100 | - |
boiling for 30 min inactivates the enzyme | Simmondsia chinensis |
pH Optimum
| pH Optimum Minimum | pH Optimum Maximum | Comment | Organism |
|---|---|---|---|
| 9 | - |
1-dodecanol | Simmondsia chinensis |
pH Range
| pH Minimum | pH Maximum | Comment | Organism |
|---|---|---|---|
| 6.6 | 9.3 | about half-maximal activity at pH 6.6 and 9.3 | Simmondsia chinensis |
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Release 2023.1 (January 2023)
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