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IUBMB CommentsIsolated from the fungus Aspergillus clavatus. The product is a sesterterpenoid (C25 terpenoid).
The enzyme appears in viruses and cellular organisms
Synonyms
ophiobolin f synthase, acla_76850,
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ACLA_76850
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(2E,6E,10E,14E)-geranylfarnesyl diphosphate + H2O = ophiobolin F + diphosphate
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(2E,6E,10E,14E)-geranylfarnesyl-diphosphate diphosphate-lyase (cyclizing, ophiobolin-F-forming)
Isolated from the fungus Aspergillus clavatus. The product is a sesterterpenoid (C25 terpenoid).
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(2E,6E,10E,14E)-geranylfarnesyl diphosphate + H2O
ophiobolin F + diphosphate
(2E,6E,10E,14E)-geranylfarnesyl diphosphate + H2O
ophiobolin F + diphosphate
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(2E,6E,10E,14E)-geranylfarnesyl diphosphate + H2O
ophiobolin F + diphosphate
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(2E,6E,10E,14E)-geranylfarnesyl diphosphate + H2O
ophiobolin F + diphosphate
(2E,6E,10E,14E)-geranylfarnesyl diphosphate + H2O
ophiobolin F + diphosphate
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(2E,6E,10E,14E)-geranylfarnesyl diphosphate + H2O
ophiobolin F + diphosphate
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Mg2+
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used in assay conditions
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brenda
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brenda
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OBLA_ASPCI
725
0
82262
Swiss-Prot
other Location (Reliability: 1)
OBLA_ASPCL
Aspergillus clavatus (strain ATCC 1007 / CBS 513.65 / DSM 816 / NCTC 3887 / NRRL 1 / QM 1276 / 107)
718
0
81603
Swiss-Prot
other Location (Reliability: 2)
OBLA_COCH5
Cochliobolus heterostrophus (strain C5 / ATCC 48332 / race O)
721
0
81421
Swiss-Prot
other Location (Reliability: 1)
OBLA_EMEVA
728
0
82233
Swiss-Prot
other Location (Reliability: 1)
A0A2U7MJ91_FUSEQ
734
0
82712
TrEMBL
other Location (Reliability: 1)
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Ni-NTA column chromatography
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expressed in Escherichia coli
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Chiba, R.; Minami, A.; Gomi, K.; Oikawa, H.
Identification of ophiobolin F synthase by a genome mining approach: a sesterterpene synthase from Aspergillus clavatus
Org. Lett.
15
594-597
2013
Aspergillus clavatus, Aspergillus clavatus NRRL 1
brenda
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