Information on EC 1.14.13.206 - laurate 7-monooxygenase

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The enzyme appears in viruses and cellular organisms

EC NUMBER
COMMENTARY hide
1.14.13.206
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RECOMMENDED NAME
GeneOntology No.
laurate 7-monooxygenase
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REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
dodecanoate + NADPH + H+ + O2 = 7-hydroxydodecanoate + NADP+ + H2O
show the reaction diagram
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PATHWAY
BRENDA Link
KEGG Link
MetaCyc Link
sporopollenin precursors biosynthesis
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SYSTEMATIC NAME
IUBMB Comments
dodecanoate,NADPH:oxygen oxidoreductase (7-hydroxylating)
This plant enzyme is involved in the synthesis of sporopollenin - a complex polymer found at the outer layer of spores and pollen. It can also act on decanoate (C10), myristate (C14), and palmitate (C16) with lower activity. The enzyme also produces a small amount of products that are hydroxylated at neighboring positions (C-6, C-8 and C-9).
ORGANISM
COMMENTARY hide
LITERATURE
UNIPROT
SEQUENCE DB
SOURCE
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Manually annotated by BRENDA team
GENERAL INFORMATION
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
malfunction
Arabidopsis CYP703A2 knockout lines show impaired pollen development and a partial male-sterile phenotype through impaired pollen wall development with absence of exine
physiological function
SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
dodecanoate + NADPH + H+ + O2
7-hydroxydodecanoate + NADP+ + H2O
show the reaction diagram
lauric acid + NADPH + H+ + O2
12-hydroxydodecanoic acid + NADP+ + H2O
show the reaction diagram
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?
NATURAL SUBSTRATES
NATURAL PRODUCTS
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
dodecanoate + NADPH + H+ + O2
7-hydroxydodecanoate + NADP+ + H2O
show the reaction diagram
COFACTOR
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
NADPH
SOURCE TISSUE
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
SOURCE
developing flower
Manually annotated by BRENDA team
Cloned/COMMENTARY
ORGANISM
UNIPROT
LITERATURE
expressed in Saccharomyces cerevisiae strain WAT1
EXPRESSION
ORGANISM
UNIPROT
LITERATURE
CYP703A3 expression is directly regulated by TDR
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