Information on EC 1.13.11.73 - methylphosphonate synthase

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The expected taxonomic range for this enzyme is: Nitrosopumilus maritimus

EC NUMBER
COMMENTARY hide
1.13.11.73
-
RECOMMENDED NAME
GeneOntology No.
methylphosphonate synthase
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REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
2-hydroxyethylphosphonate + O2 = methylphosphonate + HCO3-
show the reaction diagram
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-
-
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PATHWAY
BRENDA Link
KEGG Link
MetaCyc Link
Phosphonate and phosphinate metabolism
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-
non-pathway related
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SYSTEMATIC NAME
IUBMB Comments
2-hydroxyethylphosphonate:O2 1,2-oxidoreductase (methylphosphonate forming)
Isolated from the marine archaeon Nitrosopumilus maritimus.
ORGANISM
COMMENTARY hide
LITERATURE
UNIPROT
SEQUENCE DB
SOURCE
SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(R)-2-hydroxyethylphosphonate + O2
methylphosphonate + HCO3-
show the reaction diagram
-
-
-
-
?
(S)-2-hydroxyethylphosphonate + O2
methylphosphonate + HCO3-
show the reaction diagram
-
-
-
-
?
2-hydroxyethylphosphonate + O2
methylphosphonate + HCO3-
show the reaction diagram
METALS and IONS
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
KM VALUE [mM]
SUBSTRATE
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
0.0071
(R)-2-hydroxyethylphosphonate
-
temperature not specified in the publication, pH not specified in the publication
0.0065
(S)-2-hydroxyethylphosphonate
-
temperature not specified in the publication, pH not specified in the publication
0.0045
2-hydroxyethylphosphonate
-
temperature not specified in the publication, pH not specified in the publication
TURNOVER NUMBER [1/s]
SUBSTRATE
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
0.17
(R)-2-hydroxyethylphosphonate
Nitrosopumilus maritimus
-
temperature not specified in the publication, pH not specified in the publication
0.17
(S)-2-hydroxyethylphosphonate
Nitrosopumilus maritimus
-
temperature not specified in the publication, pH not specified in the publication
0.18
2-hydroxyethylphosphonate
Nitrosopumilus maritimus
-
temperature not specified in the publication, pH not specified in the publication
kcat/KM VALUE [1/mMs-1]
SUBSTRATE
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
24
(R)-2-hydroxyethylphosphonate
Nitrosopumilus maritimus
-
temperature not specified in the publication, pH not specified in the publication
28768
26
(S)-2-hydroxyethylphosphonate
Nitrosopumilus maritimus
-
temperature not specified in the publication, pH not specified in the publication
27246
40
2-hydroxyethylphosphonate
Nitrosopumilus maritimus
-
temperature not specified in the publication, pH not specified in the publication
3950
Cloned/COMMENTARY
ORGANISM
UNIPROT
LITERATURE
expression in Escherichia coli
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