Information on EC 1.13.11.32 - 2-nitropropane dioxygenase

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The expected taxonomic range for this enzyme is: Eukaryota, Bacteria

EC NUMBER
COMMENTARY hide
1.13.11.32
transferred to EC 1.13.12.16
RECOMMENDED NAME
GeneOntology No.
2-nitropropane dioxygenase
-
ORGANISM
COMMENTARY hide
LITERATURE
UNIPROT
SEQUENCE DB
SOURCE
SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
2 butyl-1-nitronate + O2
2 butanal + 2 nitrite
show the reaction diagram
-
-
-
-
?
2 ethylnitronate + O2
2 ethanal + 2 nitrite
show the reaction diagram
-
-
-
-
?
2 propyl-1-nitronate + O2
2 propanal + 2 nitrite
show the reaction diagram
-
-
-
-
?
ethyl nitronate + O2
ethanal + nitrite
show the reaction diagram
nitroethane + O2
ethanal + nitrite
show the reaction diagram
-
-
-
?
additional information
?
-
COFACTOR
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
INHIBITORS
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
Butanal
-
competitive inhibitor with respect to ethylnitronate as substrate
Hexanal
-
competitive inhibitor with respect to ethylnitronate as substrate
NaNO2
NaNO3
pentanal
-
competitive inhibitor with respect to ethylnitronate as substrate
propanal
-
competitive inhibitor with respect to ethylnitronate as substrate
KM VALUE [mM]
SUBSTRATE
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
additional information
additional information
-
kinetic parameters of reductive half reaction
-
TURNOVER NUMBER [1/s]
SUBSTRATE
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
additional information
additional information
Cyberlindnera mrakii
-
kinetic parameters of reductive half reaction
-
Ki VALUE [mM]
INHIBITOR
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
60
Butanal
4 - 20
KBr
11.3 - 30
KCl
77 - 125
KF
0.95 - 6
KI
9.8
NaNO2
-
pH 7.4, 30C
1.7 - 12
NaNO3
58
pentanal
Crystallization/COMMENTARY
ORGANISM
UNIPROT
LITERATURE
Cloned/COMMENTARY
ORGANISM
UNIPROT
LITERATURE
expression in Escherichia coli