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2.5.1.95: xanthan ketal pyruvate transferase

This is an abbreviated version!
For detailed information about xanthan ketal pyruvate transferase, go to the full flat file.

Reaction

phosphoenolpyruvate
+
D-Man-beta-(1->4)-D-GlcA-beta-(1->2)-D-Man-alpha-(1->3)-D-Glc-beta-(1->4)-D-Glc-alpha-1-diphospho-ditrans,octacis-undecaprenol
=
4,6-CH3(COO-)C-D-Man-beta-(1->4)-D-GlcA-beta-(1->2)-D-Man-alpha-(1->3)-D-Glc-beta-(1->4)-D-Glc-alpha-1-diphospho-ditrans,octacis-undecaprenol
+
phosphate

Synonyms

GumL, KPT

ECTree

     2 Transferases
         2.5 Transferring alkyl or aryl groups, other than methyl groups
             2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
                2.5.1.95 xanthan ketal pyruvate transferase

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Resultsin table
1Cloned(Commentary)
3General Information
2Natural Substrates/ Products (Substrates)
3Organism
1Pathway
1Reaction
3Reference
4Substrates and Products (Substrate)
2Synonyms
1Systematic Name

Natural Substrates Products

Natural Substrates Products on EC 2.5.1.95 - xanthan ketal pyruvate transferase

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NATURAL SUBSTRATE
NATURAL PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
phosphoenolpyruvate + D-Man-beta-(1->4)-D-GlcA-beta-(1->2)-D-Man-alpha-(1->3)-D-Glc-beta-(1->4)-D-Glc-alpha-1-diphospho-ditrans,octacis-undecaprenol
4,6-CH3(COO-)C-D-Man-beta-(1->4)-D-GlcA-beta-(1->2)-D-Man-alpha-(1->3)-D-Glc-beta-(1->4)-D-Glc-alpha-1-diphospho-ditrans,octacis-undecaprenol + phosphate
show the reaction diagram
-
the enzyme is involved in the biosynthesis of the polysaccharide xanthan. 30-40% of xanthan terminal mannose residues of xanthan have a 4,6-O-(1-carboxyethan-1,1-diyl) ketal group
-
-
?
phosphoenolpyruvate + xanthan
?
show the reaction diagram
-
-
-
-
?