2.5.1.88: trans,polycis-polyprenyl diphosphate synthase [(2Z,6E)-farnesyl diphosphate specific]

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For detailed information about trans,polycis-polyprenyl diphosphate synthase [(2Z,6E)-farnesyl diphosphate specific], go to the full flat file.

Reaction

ECTree

     2 Transferases

         2.5 Transferring alkyl or aryl groups, other than methyl groups

             2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)

                2.5.1.88 trans,polycis-polyprenyl diphosphate synthase [(2Z,6E)-farnesyl diphosphate specific]

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Results	in table
8	AA Sequence
1	Cloned(Commentary)
1	Organism
2	Pathway
12	PDB ID
1	pH Optimum
1	Purification (Commentary)
1	Reaction
1	Reference
5	Substrates and Products (Substrate)
1	Systematic Name
1	Temperature Optimum [°C]

Substrates Products

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Substrates Products on EC 2.5.1.88 - trans,polycis-polyprenyl diphosphate synthase [(2Z,6E)-farnesyl diphosphate specific]

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SUBSTRATE

PRODUCT                       

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

Reversibility
r=reversible
ir=irreversible
?=not specified

(2E,6E)-farnesyl diphosphate + n isopentenyl diphosphate

n diphosphate + di-trans,poly-cis-polyprenyl diphosphate

Thermobifida fusca

-

about 35% of the activity with (2Z,6E)-farnesyl diphosphate as allylic substrate

704741

broad product specificity with the major product being dodecaprenyl diphosphate. Synthesizes even C70 prenyl diphosphate as the maximum chain-length product

-

?

(2Z,6E)-farnesyl diphosphate + n isopentenyl diphosphate

n diphosphate + trans,poly-cis-polyprenyl diphosphate

Thermobifida fusca

-

highest activity with (2Z,6E)-farnesyl diphosphate as allylic substrate

704741

n = 9-11. Broad product specificity with the major product being dodecaprenyl diphosphate. Synthesizes even C70 prenyl diphosphate as the maximum chain-length product

-

?

geranyl diphosphate + n isopentenyl diphosphate

n diphosphate + trans,poly-cis-polyprenyl diphosphate

Thermobifida fusca

-

about 5% of the activity with (2Z,6E)-farnesyl diphosphate as allylic substrate

704741

broad product specificity with the major product being dodecaprenyl diphosphate. Synthesizes even C70 prenyl diphosphate as the maximum chain-length product

-

?

geranylgeranyl diphosphate + n isopentenyl diphosphate

n diphosphate + tri-trans,poly-cis-polyprenyl diphosphate

Thermobifida fusca

-

about 30% of the activity with (2Z,6E)-farnesyl diphosphate as allylic substrate

704741

broad product specificity with the major product being dodecaprenyl diphosphate. Synthesizes even C70 prenyl diphosphate as the maximum chain-length product

-

?

neryl diphosphate + n isopentenyl diphosphate

n diphosphate + poly-cis-polyprenyl diphosphate

Thermobifida fusca

-

about 10% of the activity with (2Z,6E)-farnesyl diphosphate as allylic substrate

704741

broad product specificity with the major product being dodecaprenyl diphosphate. Synthesizes even C70 prenyl diphosphate as the maximum chain-length product

-

?