2.5.1.82: hexaprenyl diphosphate synthase [geranylgeranyl-diphosphate specific]
This is an abbreviated version!
For detailed information about hexaprenyl diphosphate synthase [geranylgeranyl-diphosphate specific], go to the full flat file.
Reaction
+ 2 isopentenyl diphosphate = 2 diphosphate +
Synonyms
(all-E) hexaprenyl diphosphate synthase, (all-trans) hexaprenyl diphosphate synthase, EC 2.5.1.33, hexaprenyl pyrophosphate synthase, HexPPs, HexPS
ECTree
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Substrates Products
Substrates Products on EC 2.5.1.82 - hexaprenyl diphosphate synthase [geranylgeranyl-diphosphate specific]
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REACTION DIAGRAM
farnesyl diphosphate + 3 isopentenyl diphosphate
3 diphosphate + all-trans-hexaprenyl diphosphate
geranyl diphosphate + 4 isopentenyl diphosphate
4 diphosphate + all-trans-hexaprenyl diphosphate
-
-
-
-
?
geranylgeranyl diphosphate + 2 isopentenyl diphosphate
2 diphosphate + all-trans-hexaprenyl diphosphate
3 diphosphate + all-trans-hexaprenyl diphosphate
-
-
-
-
?
farnesyl diphosphate + 3 isopentenyl diphosphate
3 diphosphate + all-trans-hexaprenyl diphosphate
the enzyme prefers geranylgeranyl diphosphate to farnesyl diphosphate as an allylic substrate and does not show activity for geranyl diphosphate and dimethylallyl diphosphate
-
-
?
farnesyl diphosphate + 3 isopentenyl diphosphate
3 diphosphate + all-trans-hexaprenyl diphosphate
the enzyme prefers geranylgeranyl diphosphate to farnesyl diphosphate as an allylic substrate and does not show activity for geranyl diphosphate and dimethylallyl diphosphate
-
-
?
2 diphosphate + all-trans-hexaprenyl diphosphate
-
-
-
?
geranylgeranyl diphosphate + 2 isopentenyl diphosphate
2 diphosphate + all-trans-hexaprenyl diphosphate
the enzyme prefers geranylgeranyl diphosphate to farnesyl diphosphate as an allylic substrate and does not show activity for geranyl diphosphate and dimethylallyl diphosphate. The main product is hexaprenyl diphosphate (C30) when the concentrations of isopentenyl diphosphate and geranylgeranyl diphosphate are the same. A 10-fold increase in the concentration of isopentenyl diphosphate results in the increased chain length of the products: a significant amount of heptaprenyl diphosphate (C35) is produced, although hexaprenyl diphosphate remains the main product
-
-
?
geranylgeranyl diphosphate + 2 isopentenyl diphosphate
2 diphosphate + all-trans-hexaprenyl diphosphate
-
-
-
?
geranylgeranyl diphosphate + 2 isopentenyl diphosphate
2 diphosphate + all-trans-hexaprenyl diphosphate
the enzyme prefers geranylgeranyl diphosphate to farnesyl diphosphate as an allylic substrate and does not show activity for geranyl diphosphate and dimethylallyl diphosphate. The main product is hexaprenyl diphosphate (C30) when the concentrations of isopentenyl diphosphate and geranylgeranyl diphosphate are the same. A 10-fold increase in the concentration of isopentenyl diphosphate results in the increased chain length of the products: a significant amount of heptaprenyl diphosphate (C35) is produced, although hexaprenyl diphosphate remains the main product
-
-
?